Display options
Cite
Happ P, Rentschler E. Enforcement of a high-spin ground state for the first 3d heterometallic 12-metallacrown-4 complex. Dalton Trans. 2014;43(41):15308-12doi: 10.1039/c4dt02275k.
Happ, P., & Rentschler, E. (2014). Enforcement of a high-spin ground state for the first 3d heterometallic 12-metallacrown-4 complex. Dalton transactions (Cambridge, England : 2003), 43(41), 15308-12. https://doi.org/10.1039/c4dt02275k
Happ, Peter, and Rentschler, Eva. "Enforcement of a high-spin ground state for the first 3d heterometallic 12-metallacrown-4 complex." Dalton transactions (Cambridge, England : 2003) vol. 43,41 (2014): 15308-12. doi: https://doi.org/10.1039/c4dt02275k
Happ P, Rentschler E. Enforcement of a high-spin ground state for the first 3d heterometallic 12-metallacrown-4 complex. Dalton Trans. 2014 Nov 07;43(41):15308-12. doi: 10.1039/c4dt02275k. PMID: 25200695.
Copy Download .nbib Format: NLM
Share it on

Dalton Trans. 2014 Nov 07;43(41):15308-12. doi: 10.1039/c4dt02275k.

Enforcement of a high-spin ground state for the first 3d heterometallic 12-metallacrown-4 complex.

Dalton transactions (Cambridge, England : 2003)

Peter Happ, Eva Rentschler

Affiliations

  1. Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, D-55128 Mainz, Germany. [email protected].

PMID: 25200695 DOI: 10.1039/c4dt02275k

Abstract

Cu(II)(DMF)2Cl2[12-MC(Fe(III)N(Shi))-4](DMF)4·2DMF was synthesized as the first heterometallic transition metal 12-MC-4 complex. The purposeful placement of specific metal ions in the different sites of the metallacrown attains the establishment of a high-spin ground state. Inducing the anticipated superior exchange interactions, the central Cu(II) guest ion averts the common mutual cancellation of the spins, as is observed in the corresponding homometallic compounds.

Publication Types