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Reichmann TL, Ganesan R, Ipser H. Thermochemical investigations in the system Cd-Gd. J Alloys Compd. 2014;610(100):676-683doi: 10.1016/j.jallcom.2014.05.062.
Reichmann, T. L., Ganesan, R., & Ipser, H. (2014). Thermochemical investigations in the system Cd-Gd. Journal of alloys and compounds, 610(100), 676-683. https://doi.org/10.1016/j.jallcom.2014.05.062
Reichmann, Thomas L, et al. "Thermochemical investigations in the system Cd-Gd." Journal of alloys and compounds vol. 610,100 (2014): 676-683. doi: https://doi.org/10.1016/j.jallcom.2014.05.062
Reichmann TL, Ganesan R, Ipser H. Thermochemical investigations in the system Cd-Gd. J Alloys Compd. 2014 Oct 15;610(100):676-683. doi: 10.1016/j.jallcom.2014.05.062. PMID: 25328283; PMCID: PMC4106689.
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J Alloys Compd. 2014 Oct 15;610(100):676-683. doi: 10.1016/j.jallcom.2014.05.062.

Thermochemical investigations in the system Cd-Gd.

Journal of alloys and compounds

Thomas L Reichmann, Rajesh Ganesan, Herbert Ipser

Affiliations

  1. Department of Inorganic Chemistry (Materials Chemistry), University of Vienna, 1090 Vienna, Austria.
  2. Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamil Nadu, India.

PMID: 25328283 PMCID: PMC4106689 DOI: 10.1016/j.jallcom.2014.05.062

Abstract

Vapour pressure measurements were performed in terms of a non-isothermal isopiestic method to determine vapour pressures of Cd in the system Cd-Gd between 693 and 1045 K. From these results thermodynamic activities of Cd were derived as a function of temperature for the composition range 52-86 at.% Cd. By employing an adapted Gibbs-Helmholtz equation, partial molar enthalpies of mixing of Cd were obtained for the corresponding composition range, which were used to convert the activity values of Cd to a common average sample temperature of 773 K. The relatively large variation of the activity across the homogeneity ranges of the phases Cd

Keywords: Cd–Gd alloys; Isopiestic measurements; Thermodynamic properties; Vapour pressure method

References

  1. PLoS One. 2014 Apr 09;9(4):e94025 - PubMed
  2. CALPHAD. 2014 Mar;44:14-20 - PubMed

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