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Liao CW, Rao MR, Sun SS. Structural diversity of new solid-state luminophores based on quinoxaline-β-ketoiminate boron difluoride complexes with remarkable fluorescence switching properties. Chem Commun (Camb). 2015;51(13):2656-9doi: 10.1039/c4cc08958h.
Liao, C. W., Rao, M. R., & Sun, S. S. (2015). Structural diversity of new solid-state luminophores based on quinoxaline-β-ketoiminate boron difluoride complexes with remarkable fluorescence switching properties. Chemical communications (Cambridge, England), 51(13), 2656-9. https://doi.org/10.1039/c4cc08958h
Liao, Chia-Wei, et al. "Structural diversity of new solid-state luminophores based on quinoxaline-β-ketoiminate boron difluoride complexes with remarkable fluorescence switching properties." Chemical communications (Cambridge, England) vol. 51,13 (2015): 2656-9. doi: https://doi.org/10.1039/c4cc08958h
Liao CW, Rao MR, Sun SS. Structural diversity of new solid-state luminophores based on quinoxaline-β-ketoiminate boron difluoride complexes with remarkable fluorescence switching properties. Chem Commun (Camb). 2015 Feb 14;51(13):2656-9. doi: 10.1039/c4cc08958h. PMID: 25572298.
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Chem Commun (Camb). 2015 Feb 14;51(13):2656-9. doi: 10.1039/c4cc08958h.

Structural diversity of new solid-state luminophores based on quinoxaline-β-ketoiminate boron difluoride complexes with remarkable fluorescence switching properties.

Chemical communications (Cambridge, England)

Chia-Wei Liao, M Rajeswara Rao, Shih-Sheng Sun

Affiliations

  1. Institute of Chemistry, Academia Sinica, Taipei, Taiwan, Republic of China. [email protected].

PMID: 25572298 DOI: 10.1039/c4cc08958h

Abstract

A series of structurally simple yet highly tunable organoboron luminophores was designed and synthesized. The solid-state fluorescence quantum yields exhibit nearly exponential growth by decorating the luminophore with additional sterically demanding substituents. Uniquely, the luminescence of these organoboron dyes can be easily switched on/off by acidic/basic vapors, yielding a solid-state fluorescence switching function.

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