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Valiskó M, Boda D. Unraveling the behavior of the individual ionic activity coefficients on the basis of the balance of ion-ion and ion-water interactions. J Phys Chem B. 2015;119(4):1546-57doi: 10.1021/jp509445k.
Valiskó, M., & Boda, D. (2015). Unraveling the behavior of the individual ionic activity coefficients on the basis of the balance of ion-ion and ion-water interactions. The journal of physical chemistry. B, 119(4), 1546-57. https://doi.org/10.1021/jp509445k
Valiskó, Mónika, and Boda, Dezső. "Unraveling the behavior of the individual ionic activity coefficients on the basis of the balance of ion-ion and ion-water interactions." The journal of physical chemistry. B vol. 119,4 (2015): 1546-57. doi: https://doi.org/10.1021/jp509445k
Valiskó M, Boda D. Unraveling the behavior of the individual ionic activity coefficients on the basis of the balance of ion-ion and ion-water interactions. J Phys Chem B. 2015 Jan 29;119(4):1546-57. doi: 10.1021/jp509445k. Epub 2015 Jan 12. PMID: 25549274.
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J Phys Chem B. 2015 Jan 29;119(4):1546-57. doi: 10.1021/jp509445k. Epub 2015 Jan 12.

Unraveling the behavior of the individual ionic activity coefficients on the basis of the balance of ion-ion and ion-water interactions.

The journal of physical chemistry. B

Mónika Valiskó, Dezső Boda

Affiliations

  1. Department of Physical Chemistry, University of Pannonia , P.O. Box 158, H-8201 Veszprém, Hungary.

PMID: 25549274 DOI: 10.1021/jp509445k

Abstract

We investigate the individual activity coefficients of pure 1:1 and 2:1 electrolytes using our theory that is based on the competition of ion-ion (II) and ion-water (IW) interactions (Vincze et al. J. Chem. Phys. 2010, 133, 154507). The II term is computed from grand canonical Monte Carlo simulations on the basis of the implicit solvent model of electrolytes using hard sphere ions with Pauling radii. The IW term is computed on the basis of Born's treatment of solvation using experimental hydration free energies. The two terms are coupled through the concentration-dependent dielectric constant of the electrolyte. We show that the theory can provide valuable insight into the nonmonotonic concentration dependence of individual activity coefficients. We compare our theoretical predictions against experimental data measured by electrochemical cells containing ion-specific electrodes. We find good agreement for 2:1 electrolytes, while the accuracy is worse for 1:1 systems. This deviation in accuracy is explained by the fact that the two competing terms (II and IW) are much larger in the 2:1 case, resulting in smaller relative errors. The difference of the excess chemical potentials of cations and anions is determined by asymmetries in the properties of the two ions: charge, radius, and hydration free energies.

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