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Jantschke A, Spinde K, Brunner E. Electrostatic interplay: The interaction triangle of polyamines, silicic acid, and phosphate studied through turbidity measurements, silicomolybdic acid test, and (29)Si NMR spectroscopy. Beilstein J Nanotechnol. 2014;5:2026-35doi: 10.3762/bjnano.5.211.
Jantschke, A., Spinde, K., & Brunner, E. (2014). Electrostatic interplay: The interaction triangle of polyamines, silicic acid, and phosphate studied through turbidity measurements, silicomolybdic acid test, and (29)Si NMR spectroscopy. Beilstein journal of nanotechnology, 52026-35. https://doi.org/10.3762/bjnano.5.211
Jantschke, Anne, et al. "Electrostatic interplay: The interaction triangle of polyamines, silicic acid, and phosphate studied through turbidity measurements, silicomolybdic acid test, and (29)Si NMR spectroscopy." Beilstein journal of nanotechnology vol. 5 (2014): 2026-35. doi: https://doi.org/10.3762/bjnano.5.211
Jantschke A, Spinde K, Brunner E. Electrostatic interplay: The interaction triangle of polyamines, silicic acid, and phosphate studied through turbidity measurements, silicomolybdic acid test, and (29)Si NMR spectroscopy. Beilstein J Nanotechnol. 2014 Nov 06;5:2026-35. doi: 10.3762/bjnano.5.211. eCollection 2014. PMID: 25551030; PMCID: PMC4273220.
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Beilstein J Nanotechnol. 2014 Nov 06;5:2026-35. doi: 10.3762/bjnano.5.211. eCollection 2014.

Electrostatic interplay: The interaction triangle of polyamines, silicic acid, and phosphate studied through turbidity measurements, silicomolybdic acid test, and (29)Si NMR spectroscopy.

Beilstein journal of nanotechnology

Anne Jantschke, Katrin Spinde, Eike Brunner

Affiliations

  1. TU Dresden, Fachrichtung Chemie und Lebensmittelchemie, Bioanalytische Chemie, 01062 Dresden, Germany.

PMID: 25551030 PMCID: PMC4273220 DOI: 10.3762/bjnano.5.211

Abstract

The discovery of long-chain polyamines as biomolecules that are tightly associated to biosilica in diatom cell walls has inspired numerous in vitro studies aiming to characterize polyamine-silica interactions. The determination of these interactions at the molecular level is of fundamental interest on one hand for the understanding of cell wall biogenesis in diatoms and on the other hand for designing bioinspired materials synthesis approaches. The present contribution deals with the influence of amines and polyamines upon the initial self-assembly processes taking place during polyamine-mediated silica formation in solution. The influence of phosphate upon these processes is studied. For this purpose, sodium metasilicate solutions containing additives such as polyallylamine, allylamine and others in the presence/absence of phosphate were investigated. The analyses are based mainly on turbidity measurements yielding information about the early aggregation steps which finally give rise to the formation and precipitation of silica.

Keywords: 29Si NMR; phosphate; self-assembly; silica–polyamine interactions; silicomolybdic acid test; turbidity measurements

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