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Phys Chem Chem Phys. 2015 Mar 07;17(9):6227-32. doi: 10.1039/c4cp05995f.

Nitrogen-doped carbon nanoparticles derived from acrylonitrile plasma for electrochemical oxygen reduction.

Physical chemistry chemical physics : PCCP

Gasidit Panomsuwan, Nagahiro Saito, Takahiro Ishizaki

Affiliations

  1. Department of Materials Science and Engineering, Faculty of Engineering, Shibaura Institute of Technology, Tokyo 135-8548, Japan. [email protected] [email protected].

PMID: 25661238 DOI: 10.1039/c4cp05995f

Abstract

Nitrogen-doped carbon nanoparticles were synthesized via a solution plasma process, with acrylonitrile as a single-source precursor, followed by a post-thermal annealing process. The nitrogen-bonding states can be tuned by varying the annealing temperature. The best electrocatalytic activity for oxygen reduction reaction (ORR) in terms of both onset potential and limiting current density can be achieved for the catalyst annealed at an optimal temperature of 800 °C because of the high content of graphitic-N catalytic sites and a large specific surface area.

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