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Yan SY, Liu YJ, Liu B, et al. Nickel-catalyzed thiolation of unactivated aryl C-H bonds: efficient access to diverse aryl sulfides. Chem Commun (Camb). 2015;51(19):4069-72doi: 10.1039/c4cc10446c.
Yan, S. Y., Liu, Y. J., Liu, B., Liu, Y. H., & Shi, B. F. (2015). Nickel-catalyzed thiolation of unactivated aryl C-H bonds: efficient access to diverse aryl sulfides. Chemical communications (Cambridge, England), 51(19), 4069-72. https://doi.org/10.1039/c4cc10446c
Yan, Sheng-Yi, et al. "Nickel-catalyzed thiolation of unactivated aryl C-H bonds: efficient access to diverse aryl sulfides." Chemical communications (Cambridge, England) vol. 51,19 (2015): 4069-72. doi: https://doi.org/10.1039/c4cc10446c
Yan SY, Liu YJ, Liu B, Liu YH, Shi BF. Nickel-catalyzed thiolation of unactivated aryl C-H bonds: efficient access to diverse aryl sulfides. Chem Commun (Camb). 2015 Mar 07;51(19):4069-72. doi: 10.1039/c4cc10446c. PMID: 25661824.
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Chem Commun (Camb). 2015 Mar 07;51(19):4069-72. doi: 10.1039/c4cc10446c.

Nickel-catalyzed thiolation of unactivated aryl C-H bonds: efficient access to diverse aryl sulfides.

Chemical communications (Cambridge, England)

Sheng-Yi Yan, Yue-Jin Liu, Bin Liu, Yan-Hua Liu, Bing-Feng Shi

Affiliations

  1. Department of Chemistry, Zhejiang University, Hangzhou 310027, China. [email protected].

PMID: 25661824 DOI: 10.1039/c4cc10446c

Abstract

A nickel-catalyzed thiolation of unactivated C(sp(2))-H bonds with disulfides employing the PIP directing group was described. This process uses a catalytic nickel catalyst and no metallic oxidants or cocatalysts are required. The reaction tolerates various important functional groups and heteroarenes, providing an efficient synthetic pathway to access diverse diaryl sulfides.

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