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Delpont N, Escofet I, Pérez-Galán P, et al. Modular chiral gold(i) phosphite complexes†Electronic supplementary information (ESI) available: Experimental results and NMR data. CCDC 933751 (. Catal Sci Technol. 2013;3(11):3007-3012doi: 10.1039/c3cy00250k.
Delpont, N., Escofet, I., Pérez-Galán, P., Spiegl, D., Raducan, M., Bour, C., Sinisi, R., & Echavarren, A. M. (2013). Modular chiral gold(i) phosphite complexes†Electronic supplementary information (ESI) available: Experimental results and NMR data. CCDC 933751 (. Catalysis science & technology, 3(11), 3007-3012. https://doi.org/10.1039/c3cy00250k
Delpont, Nicolas, et al. "Modular chiral gold(i) phosphite complexes†Electronic supplementary information (ESI) available: Experimental results and NMR data. CCDC 933751 (." Catalysis science & technology vol. 3,11 (2013): 3007-3012. doi: https://doi.org/10.1039/c3cy00250k
Delpont N, Escofet I, Pérez-Galán P, Spiegl D, Raducan M, Bour C, Sinisi R, Echavarren AM. Modular chiral gold(i) phosphite complexes†Electronic supplementary information (ESI) available: Experimental results and NMR data. CCDC 933751 (. Catal Sci Technol. 2013 Oct 07;3(11):3007-3012. doi: 10.1039/c3cy00250k. Epub 2013 Jul 22. PMID: 25664164; PMCID: PMC4317972.
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Catal Sci Technol. 2013 Oct 07;3(11):3007-3012. doi: 10.1039/c3cy00250k. Epub 2013 Jul 22.

Modular chiral gold(i) phosphite complexes†Electronic supplementary information (ESI) available: Experimental results and NMR data. CCDC 933751 (.

Catalysis science & technology

Nicolas Delpont, Imma Escofet, Patricia Pérez-Galán, Dirk Spiegl, Mihai Raducan, Christophe Bour, Riccardo Sinisi, Antonio M Echavarren

Affiliations

  1. Institute of Chemical Research of Catalonia (ICIQ) , Av. Països Catalans 16 , 43007 Tarragona , Spain . Email: [email protected].
  2. Institute of Chemical Research of Catalonia (ICIQ) , Av. Països Catalans 16 , 43007 Tarragona , Spain . Email: [email protected] ; Departament de Química Analítica i Química Orgànica , Universitat Rovira i Virgili , C/Marcel·li Domingo s/n , 43007 Tarragona , Spain.

PMID: 25664164 PMCID: PMC4317972 DOI: 10.1039/c3cy00250k

Abstract

Chiral gold(i) phosphite complexes are readily prepared modularly from 3,3'-bis(triphenylsilyl)-1,1'-bi-2-naphthol. These chiral gold(i) phosphite complexes are very reactive precatalysts for the [4+2] cycloaddition of aryl-substituted 1,6-enynes with enantiomeric ratios ranging from 86 : 14 up to 94 : 6.

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