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Pengo P, Bazzo C, Boccalon M, et al. Differential reactivity of the inner and outer positions of Au25(SCH2CH2Ph)18 dimeric staples under place exchange conditions. Chem Commun (Camb). 2015;51(15):3204-7doi: 10.1039/c4cc09252j.
Pengo, P., Bazzo, C., Boccalon, M., & Pasquato, L. (2015). Differential reactivity of the inner and outer positions of Au25(SCH2CH2Ph)18 dimeric staples under place exchange conditions. Chemical communications (Cambridge, England), 51(15), 3204-7. https://doi.org/10.1039/c4cc09252j
Pengo, Paolo, et al. "Differential reactivity of the inner and outer positions of Au25(SCH2CH2Ph)18 dimeric staples under place exchange conditions." Chemical communications (Cambridge, England) vol. 51,15 (2015): 3204-7. doi: https://doi.org/10.1039/c4cc09252j
Pengo P, Bazzo C, Boccalon M, Pasquato L. Differential reactivity of the inner and outer positions of Au25(SCH2CH2Ph)18 dimeric staples under place exchange conditions. Chem Commun (Camb). 2015 Feb 21;51(15):3204-7. doi: 10.1039/c4cc09252j. PMID: 25605034.
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Chem Commun (Camb). 2015 Feb 21;51(15):3204-7. doi: 10.1039/c4cc09252j.

Differential reactivity of the inner and outer positions of Au25(SCH2CH2Ph)18 dimeric staples under place exchange conditions.

Chemical communications (Cambridge, England)

Paolo Pengo, Cristian Bazzo, Mariangela Boccalon, Lucia Pasquato

Affiliations

  1. Department of Chemical and Pharmaceutical Sciences, University of Trieste, Via L. Giorgieri 1, I-34127 Trieste, Italy. [email protected] [email protected].

PMID: 25605034 DOI: 10.1039/c4cc09252j

Abstract

The kinetic analysis of the place exchange reaction on the neutral Au25(SCH2CH2Ph)18 cluster by using 4-fluorobenzylthiol and a series of substituted arylthiols allowed us to establish, for the first time, that the selectivity for the inner and outer positions of the dimeric staples of the cluster can be modulated by using incoming thiols with different structures.

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