Display options
Cite
Chorazy S, Podgajny R, Nakabayashi K, et al. Fe(II) spin-crossover phenomenon in the pentadecanuclear {Fe9[Re(CN)8]6} spherical cluster. Angew Chem Int Ed Engl. 2015;54(17):5093-7doi: 10.1002/anie.201500288.
Chorazy, S., Podgajny, R., Nakabayashi, K., Stanek, J., Rams, M., Sieklucka, B., & Ohkoshi, S. (2015). Fe(II) spin-crossover phenomenon in the pentadecanuclear {Fe9[Re(CN)8]6} spherical cluster. Angewandte Chemie (International ed. in English), 54(17), 5093-7. https://doi.org/10.1002/anie.201500288
Chorazy, Szymon, et al. "Fe(II) spin-crossover phenomenon in the pentadecanuclear {Fe9[Re(CN)8]6} spherical cluster." Angewandte Chemie (International ed. in English) vol. 54,17 (2015): 5093-7. doi: https://doi.org/10.1002/anie.201500288
Chorazy S, Podgajny R, Nakabayashi K, Stanek J, Rams M, Sieklucka B, Ohkoshi S. Fe(II) spin-crossover phenomenon in the pentadecanuclear {Fe9[Re(CN)8]6} spherical cluster. Angew Chem Int Ed Engl. 2015 Apr 20;54(17):5093-7. doi: 10.1002/anie.201500288. Epub 2015 Mar 03. PMID: 25736811.
Copy Download .nbib Format: NLM
Share it on

Angew Chem Int Ed Engl. 2015 Apr 20;54(17):5093-7. doi: 10.1002/anie.201500288. Epub 2015 Mar 03.

Fe(II) spin-crossover phenomenon in the pentadecanuclear {Fe9[Re(CN)8]6} spherical cluster.

Angewandte Chemie (International ed. in English)

Szymon Chorazy, Robert Podgajny, Koji Nakabayashi, Jan Stanek, Michał Rams, Barbara Sieklucka, Shin-Ichi Ohkoshi

Affiliations

  1. Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo113-0033 (Japan) Homepage: http://www.chem.s.u-tokyo.ac.jp/users/ssphys/english/; Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków (Poland). [email protected].

PMID: 25736811 DOI: 10.1002/anie.201500288

Abstract

The self-assembly of iron(II) ions with rare octacyanidorhenate(V) metalloligands in a methanolic solution results in the formation of a nanometric pentadecanuclear {Fe(II) 9 [Re(V) (CN)8 ]6 (MeOH)24 }⋅10 MeOH (1) molecule with a six-capped body-centered cubic topology. The cluster demonstrates a thermally-induced spin-crossover phase transition at T1/2 =195 K which occurs selectively for a single Fe(II)  ion embedded in the center of a cluster core.

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: cluster compounds; cyanide ligands; iron; rhenium; spin crossover

Publication Types