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Dalton Trans. 2015 Apr 07;44(13):5974-7. doi: 10.1039/c5dt00431d.

Solvent-free synthesis of new inorganic-organic hybrid solids with finely tuned manganese oxalate structures.

Dalton transactions (Cambridge, England : 2003)

Lindong Luan, Jing Li, Changzhen Yin, Zhien Lin, Hui Huang

Affiliations

  1. School of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China. [email protected].

PMID: 25742937 DOI: 10.1039/c5dt00431d

Abstract

Three manganese phosphate-oxalates have been synthesized under solvent-free conditions. These inorganic-organic hybrid solids are based on a pcu-type topology with nanobelt-like, sql-, and cds-type manganese oxalate skeletons, respectively. The amine molecules play a novel structure-directing role for the formation of different metal-organic skeletons within a specific framework topology.

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