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Heard KW, Morrison JJ, Weston L, et al. An orthogonal C-H borylation--cross-coupling strategy for the preparation of tetrasubstituted "A2B2"-chrysene derivatives with tuneable photophysical properties. Chem Commun (Camb). 2015;51(28):6115-8doi: 10.1039/c4cc10132d.
Heard, K. W., Morrison, J. J., Weston, L., Lo, C. H., Pirvu, L., Raftery, J., Little, M. S., McDouall, J. J., Yeates, S. G., & Quayle, P. (2015). An orthogonal C-H borylation--cross-coupling strategy for the preparation of tetrasubstituted "A2B2"-chrysene derivatives with tuneable photophysical properties. Chemical communications (Cambridge, England), 51(28), 6115-8. https://doi.org/10.1039/c4cc10132d
Heard, K W J, et al. "An orthogonal C-H borylation--cross-coupling strategy for the preparation of tetrasubstituted "A2B2"-chrysene derivatives with tuneable photophysical properties." Chemical communications (Cambridge, England) vol. 51,28 (2015): 6115-8. doi: https://doi.org/10.1039/c4cc10132d
Heard KW, Morrison JJ, Weston L, Lo CH, Pirvu L, Raftery J, Little MS, McDouall JJ, Yeates SG, Quayle P. An orthogonal C-H borylation--cross-coupling strategy for the preparation of tetrasubstituted "A2B2"-chrysene derivatives with tuneable photophysical properties. Chem Commun (Camb). 2015 Apr 11;51(28):6115-8. doi: 10.1039/c4cc10132d. PMID: 25745672.
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Chem Commun (Camb). 2015 Apr 11;51(28):6115-8. doi: 10.1039/c4cc10132d.

An orthogonal C-H borylation--cross-coupling strategy for the preparation of tetrasubstituted "A2B2"-chrysene derivatives with tuneable photophysical properties.

Chemical communications (Cambridge, England)

K W J Heard, J J Morrison, L Weston, C H Lo, L Pirvu, J Raftery, M S Little, J J W McDouall, S G Yeates, P Quayle

Affiliations

  1. School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK. [email protected].

PMID: 25745672 DOI: 10.1039/c4cc10132d

Abstract

The regioselective, orthogonal functionalisation of 4,10-dichlorochrysene enables the synthesis of a variety of 2,8,4,10-"A2B2"-tetrasubstituted chrysenes. Such compounds exhibit broadened UV-vis absorption spectra, decreased band gap and higher HOMO levels compared to the parent chrysene.

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