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Ma Y, Yeh LH, Lin CY, et al. pH-regulated ionic conductance in a nanochannel with overlapped electric double layers. Anal Chem. 2015;87(8):4508-14doi: 10.1021/acs.analchem.5b00536.
Ma, Y., Yeh, L. H., Lin, C. Y., Mei, L., & Qian, S. (2015). pH-regulated ionic conductance in a nanochannel with overlapped electric double layers. Analytical chemistry, 87(8), 4508-14. https://doi.org/10.1021/acs.analchem.5b00536
Ma, Yu, et al. "pH-regulated ionic conductance in a nanochannel with overlapped electric double layers." Analytical chemistry vol. 87,8 (2015): 4508-14. doi: https://doi.org/10.1021/acs.analchem.5b00536
Ma Y, Yeh LH, Lin CY, Mei L, Qian S. pH-regulated ionic conductance in a nanochannel with overlapped electric double layers. Anal Chem. 2015 Apr 21;87(8):4508-14. doi: 10.1021/acs.analchem.5b00536. Epub 2015 Apr 03. PMID: 25803424.
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Anal Chem. 2015 Apr 21;87(8):4508-14. doi: 10.1021/acs.analchem.5b00536. Epub 2015 Apr 03.

pH-regulated ionic conductance in a nanochannel with overlapped electric double layers.

Analytical chemistry

Yu Ma, Li-Hsien Yeh, Chih-Yuan Lin, Lanju Mei, Shizhi Qian

Affiliations

  1. †School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, P. R. China.
  2. ‡Department of Chemical and Materials Engineering, National Yunlin University of Science and Technology, Yunlin 64002, Taiwan.
  3. §Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan.
  4. ?Institute of Micro/Nanotechnology, Old Dominion University, Norfolk, Virginia 23529, United States.

PMID: 25803424 DOI: 10.1021/acs.analchem.5b00536

Abstract

Accurately and rapidly analyzing the ionic current/conductance in a nanochannel, especially under the condition of overlapped electric double layers (EDLs), is of fundamental significance for the design and development of novel nanofluidic devices. To achieve this, an analytical model for the surface charge properties and ionic current/conductance in a pH-regulated nanochannel is developed for the first time. The developed model takes into account the effects of the EDL overlap, electroosmotic flow, Stern layer, multiple ionic species, and the site dissociation/association reactions on the channel walls. In addition to good agreement with the existing experimental data of nanochannel conductance available from the literature, our analytical model is also validated by the full model with the Poisson-Nernst-Planck and Navier-Stokes equations. The EDL overlap effect is significant at small nanochannel height, low salt concentration, and medium low pH. Neglecting the EDL overlap effect could result in a wrong estimation in the zeta potential and conductance of the nanochannel in a single measurement.

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