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Smith BJ, Hwang N, Chavez AD, et al. Growth rates and water stability of 2D boronate ester covalent organic frameworks. Chem Commun (Camb). 2015;51(35):7532-5doi: 10.1039/c5cc00379b.
Smith, B. J., Hwang, N., Chavez, A. D., Novotney, J. L., & Dichtel, W. R. (2015). Growth rates and water stability of 2D boronate ester covalent organic frameworks. Chemical communications (Cambridge, England), 51(35), 7532-5. https://doi.org/10.1039/c5cc00379b
Smith, Brian J, et al. "Growth rates and water stability of 2D boronate ester covalent organic frameworks." Chemical communications (Cambridge, England) vol. 51,35 (2015): 7532-5. doi: https://doi.org/10.1039/c5cc00379b
Smith BJ, Hwang N, Chavez AD, Novotney JL, Dichtel WR. Growth rates and water stability of 2D boronate ester covalent organic frameworks. Chem Commun (Camb). 2015 May 01;51(35):7532-5. doi: 10.1039/c5cc00379b. PMID: 25848654.
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Chem Commun (Camb). 2015 May 01;51(35):7532-5. doi: 10.1039/c5cc00379b.

Growth rates and water stability of 2D boronate ester covalent organic frameworks.

Chemical communications (Cambridge, England)

Brian J Smith, Nicky Hwang, Anton D Chavez, Jennifer L Novotney, William R Dichtel

Affiliations

  1. Department of Chemistry and Chemical Biology, Cornell University, Baker Laboratory, Ithaca, New York 14853-1301, USA. [email protected].

PMID: 25848654 DOI: 10.1039/c5cc00379b

Abstract

We examine the growth rates, activation energies, and hydrolytic stability of multiple 2D boronate ester covalent organic frameworks by turbidity measurements, observing a 200-fold range in stability. The rate-determining step in boronate ester 2D COF growth is not in-solution condensation, but rather interlayer polymer stacking through a nucleation-elongation process.

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