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Chan KC, Chu WK, Yiu SM, et al. Synthesis, characterization, photophysics and electrochemical study of luminescent iridium(III) complexes with isocyanoborate ligands. Dalton Trans. 2015;44(34):15135-44doi: 10.1039/c5dt00904a.
Chan, K. C., Chu, W. K., Yiu, S. M., & Ko, C. C. (2015). Synthesis, characterization, photophysics and electrochemical study of luminescent iridium(III) complexes with isocyanoborate ligands. Dalton transactions (Cambridge, England : 2003), 44(34), 15135-44. https://doi.org/10.1039/c5dt00904a
Chan, Kin-Cheung, et al. "Synthesis, characterization, photophysics and electrochemical study of luminescent iridium(III) complexes with isocyanoborate ligands." Dalton transactions (Cambridge, England : 2003) vol. 44,34 (2015): 15135-44. doi: https://doi.org/10.1039/c5dt00904a
Chan KC, Chu WK, Yiu SM, Ko CC. Synthesis, characterization, photophysics and electrochemical study of luminescent iridium(III) complexes with isocyanoborate ligands. Dalton Trans. 2015 Sep 14;44(34):15135-44. doi: 10.1039/c5dt00904a. PMID: 25939478.
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Dalton Trans. 2015 Sep 14;44(34):15135-44. doi: 10.1039/c5dt00904a.

Synthesis, characterization, photophysics and electrochemical study of luminescent iridium(III) complexes with isocyanoborate ligands.

Dalton transactions (Cambridge, England : 2003)

Kin-Cheung Chan, Wing-Kin Chu, Shek-Man Yiu, Chi-Chiu Ko

Affiliations

  1. Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China. [email protected].

PMID: 25939478 DOI: 10.1039/c5dt00904a

Abstract

A new series of cyclometalated iridium(III) complexes with isocyanoborate ligands [Ir(R2ppy)2(L)(CNBR'3)] (R = H or F; L = CNC6H4Cl-4 or PPh3; R' = Ph, C6F5 or C6H4Cl-4), [Ir(biqb)(ppy)(CNBR''3)] (R'' = C6F5 or C6H4Cl-4) and {Ir(ppy)2(CN)n[CNB(C6F5)3]2-n}(-) (n = 0 or 1) have been synthesized and characterized. Three of these complexes have also been structurally characterized by X-ray crystallography. The photophysical and electrochemical properties of these complexes have been investigated. The effects of isocyanoborate ligands on the luminescence properties of these iridium(III) complexes are also described.

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