J Nanosci Nanotechnol. 2014 Aug;14(8):6146-9. doi: 10.1166/jnn.2014.8457.

Anisotropic thermal conductive MWCNT/polymer composites prepared with an immiscible PS/LDPE blend.

Journal of nanoscience and nanotechnology

Younghwan Kwon

PMID: 25936075 DOI: 10.1166/jnn.2014.8457

Abstract

This study focuses on MWCNT/polymer composites with flexible, anisotropic heat transporting properties. For this study, an immiscible polymer blend of MWCNT/PS and LDPE (13.5:86.5 v:v) were used as a template. MWCNT/PS composites were first prepared by a solution process, and then melt-blended with LDPE using a brabender mixer. For achieving an alignment of MWCNT/PS in LDPE matrix, the blends of MWCNT/PS and LDPE were continuously treated under a fixed shear rate of 10 s(-1) at 210 °C. With partial extraction of PS in the aligned blends, FE-SEM images of the aligned blends revealed morphology of MWCNT in the PS/LDPE matrix, indicating local distribution of MWCNT selectively inside PS, where PS was elongated parallel to shear direction in LDPE matrix. The prepared MWCNT/PS and LDPE blends showed an anisotropic heat transporting behavior with anisotropic ratio of thermal conductivity (AR = λx/λz) up to 1.330 at 10 wt% of MWCNT in PS (equivalent to 1.50 wt% of MWCNT in PS/LDPE).

Publication Types

• Journal Article
• Research Support, Non-U.S. Gov't