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Arrowsmith M, Hill MS, Johnson AL, et al. Attenuated Organomagnesium Activation of White Phosphorus. Angew Chem Int Ed Engl. 2015;54(27):7882-5doi: 10.1002/anie.201503065.
Arrowsmith, M., Hill, M. S., Johnson, A. L., Kociok-Köhn, G., & Mahon, M. F. (2015). Attenuated Organomagnesium Activation of White Phosphorus. Angewandte Chemie (International ed. in English), 54(27), 7882-5. https://doi.org/10.1002/anie.201503065
Arrowsmith, Merle, et al. "Attenuated Organomagnesium Activation of White Phosphorus." Angewandte Chemie (International ed. in English) vol. 54,27 (2015): 7882-5. doi: https://doi.org/10.1002/anie.201503065
Arrowsmith M, Hill MS, Johnson AL, Kociok-Köhn G, Mahon MF. Attenuated Organomagnesium Activation of White Phosphorus. Angew Chem Int Ed Engl. 2015 Jun 26;54(27):7882-5. doi: 10.1002/anie.201503065. Epub 2015 May 27. PMID: 26014162; PMCID: PMC4648029.
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Angew Chem Int Ed Engl. 2015 Jun 26;54(27):7882-5. doi: 10.1002/anie.201503065. Epub 2015 May 27.

Attenuated Organomagnesium Activation of White Phosphorus.

Angewandte Chemie (International ed. in English)

Merle Arrowsmith, Michael S Hill, Andrew L Johnson, Gabriele Kociok-Köhn, Mary F Mahon

Affiliations

  1. Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY (UK).
  2. Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY (UK). [email protected].

PMID: 26014162 PMCID: PMC4648029 DOI: 10.1002/anie.201503065

Abstract

Sequential reactions between a 2,6-diisopropylphenyl-substituted β-diketiminato magnesium n-butyl derivative and P4 allow the highly discriminating synthesis of unusual [nBu2P4](2-) and [nBu2P8](2-) cluster dianions.

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: P4 activation; cluster compounds; magnesium; phosphorus; structure elucidation

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