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Leach EG, Kulesza AA, Staples RJ, et al. Crystal structures of 1-(4-chloro-phen-yl)-2-(di-phenyl-phosphor-yl)ethan-1-one and 1-(di-phenyl-phosphor-yl)-3,3-di-methyl-butan-2-one. Acta Crystallogr E Crystallogr Commun. 2015;71:523-7doi: 10.1107/S2056989015006994.
Leach, E. G., Kulesza, A. A., Staples, R. J., & Biros, S. M. (2015). Crystal structures of 1-(4-chloro-phen-yl)-2-(di-phenyl-phosphor-yl)ethan-1-one and 1-(di-phenyl-phosphor-yl)-3,3-di-methyl-butan-2-one. Acta crystallographica. Section E, Crystallographic communications, 71523-7. https://doi.org/10.1107/S2056989015006994
Leach, Erin G, et al. "Crystal structures of 1-(4-chloro-phen-yl)-2-(di-phenyl-phosphor-yl)ethan-1-one and 1-(di-phenyl-phosphor-yl)-3,3-di-methyl-butan-2-one." Acta crystallographica. Section E, Crystallographic communications vol. 71 (2015): 523-7. doi: https://doi.org/10.1107/S2056989015006994
Leach EG, Kulesza AA, Staples RJ, Biros SM. Crystal structures of 1-(4-chloro-phen-yl)-2-(di-phenyl-phosphor-yl)ethan-1-one and 1-(di-phenyl-phosphor-yl)-3,3-di-methyl-butan-2-one. Acta Crystallogr E Crystallogr Commun. 2015 Apr 22;71:523-7. doi: 10.1107/S2056989015006994. eCollection 2015 May 01. PMID: 25995871; PMCID: PMC4420131.
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Acta Crystallogr E Crystallogr Commun. 2015 Apr 22;71:523-7. doi: 10.1107/S2056989015006994. eCollection 2015 May 01.

Crystal structures of 1-(4-chloro-phen-yl)-2-(di-phenyl-phosphor-yl)ethan-1-one and 1-(di-phenyl-phosphor-yl)-3,3-di-methyl-butan-2-one.

Acta crystallographica. Section E, Crystallographic communications

Erin G Leach, Alyssa A Kulesza, Richard J Staples, Shannon M Biros

Affiliations

  1. Department of Chemistry, Grand Valley State University, 1 Campus Dr., Allendale, MI 49401, USA.
  2. Center for Crystallographic Research, Department of Chemistry, Michigan State University, 578 S. Shaw Lane, East Lansing, MI 48824, USA.

PMID: 25995871 PMCID: PMC4420131 DOI: 10.1107/S2056989015006994

Abstract

The title compounds, C20H16ClO2P, (I), and C18H21O2P, (II), were synthesized via an Arbuzov reaction between an α-bromo-ketone and isopropoxydi-phenyl-phosphane. In the crystals of both compounds, mol-ecules are linked via bifurcated C-H⋯(O,O) hydrogen bonds, forming chains propagating along [100] for (I) and along [010] for (II). The chains are linked via C-H⋯π inter-actions, leading to the formation of sheets lying parallel to (010) for (I) and (001) for (II). The absolute structure of compound (II) was determined by resonant scattering [Flack parameter = 0.088 (14)].

Keywords: C—H⋯O hydrogen bonds; C—H⋯π inter­actions; carbamoyl­methyl­phosphane oxide (CMPO); crystal structure; isopropoxydi­phenyl­phosphane; α-bromo­ketone

References

  1. Anal Bioanal Chem. 2009 May;394(1):107-20 - PubMed
  2. Acta Crystallogr A Found Adv. 2015 Jan;71(Pt 1):59-75 - PubMed
  3. Org Biomol Chem. 2005 Feb 21;3(4):630-7 - PubMed
  4. Acta Crystallogr C Struct Chem. 2015 Jan;71(Pt 1):3-8 - PubMed
  5. Inorg Chem. 2013 Mar 18;52(6):3063-83 - PubMed
  6. Chem Soc Rev. 2010 Jan;39(1):189-227 - PubMed
  7. Angew Chem Int Ed Engl. 2014 Jan 13;53(3):662-71 - PubMed
  8. Acta Crystallogr B Struct Sci Cryst Eng Mater. 2013 Jun;69(Pt 3):249-59 - PubMed
  9. Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22 - PubMed

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