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McDonald C, Williams DW, Comar P, et al. Molecular Pac-Man and Tacos: layered Cu(II) cages from ligands with high binding site concentrations. Dalton Trans. 2015;44(29):13359-68doi: 10.1039/c5dt01463h.
McDonald, C., Williams, D. W., Comar, P., Coles, S. J., Keene, T. D., Pitak, M. B., Brechin, E. K., & Jones, L. F. (2015). Molecular Pac-Man and Tacos: layered Cu(II) cages from ligands with high binding site concentrations. Dalton transactions (Cambridge, England : 2003), 44(29), 13359-68. https://doi.org/10.1039/c5dt01463h
McDonald, Cecelia, et al. "Molecular Pac-Man and Tacos: layered Cu(II) cages from ligands with high binding site concentrations." Dalton transactions (Cambridge, England : 2003) vol. 44,29 (2015): 13359-68. doi: https://doi.org/10.1039/c5dt01463h
McDonald C, Williams DW, Comar P, Coles SJ, Keene TD, Pitak MB, Brechin EK, Jones LF. Molecular Pac-Man and Tacos: layered Cu(II) cages from ligands with high binding site concentrations. Dalton Trans. 2015 Aug 07;44(29):13359-68. doi: 10.1039/c5dt01463h. PMID: 26133039.
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Dalton Trans. 2015 Aug 07;44(29):13359-68. doi: 10.1039/c5dt01463h.

Molecular Pac-Man and Tacos: layered Cu(II) cages from ligands with high binding site concentrations.

Dalton transactions (Cambridge, England : 2003)

Cecelia McDonald, David W Williams, Priyanka Comar, Simon J Coles, Tony D Keene, Mateusz B Pitak, Euan K Brechin, Leigh F Jones

Affiliations

  1. School of Chemistry, NUI Galway, University Road, Galway, Ireland.

PMID: 26133039 DOI: 10.1039/c5dt01463h

Abstract

The in situ formation and subsequent Cu(ii) ligation of the polydentate pro-ligands o-[(E)-(2-hydroxy-3-methoxyphenyl)methylideneamino]benzohydroxamic acid (L1H3), o-[(E)-(2-hydroxy-3-methoxy-5-bromophenyl)methylideneamino]benzohydroxamic acid (L2H3) and o-[(E)-(2-hydroxyphenyl)methylideneamino]benzohydroxamic acid (L3H3), leads to the self-assembly of the cages [Cu(ii)10(L1)4(2-aph)2(H2O)2](ClO4)4·5MeOH (), [Cu(ii)14(L1)8(MeOH)2.5(H2O)7.5](NO3)4·3MeOH·7H2O (), [Cu(ii)14(L2)8(MeOH)4(H2O)6](NO3)4·6H2O (), [Cu(ii)14(L3)8(MeOH)6(H2O)2](NO3)4·4MeOH·8H2O () and [Cu(ii)30O(OH)4(OMe)2(L1)16(MeOH)4(H2O)2](ClO4)4·2MeOH·30H2O (). Each member comprises a highly unusual topology derived from off-set, stacked, near planar layers of polynuclear subunits connected through long Cu(ii)-O contacts. The exact topology observed is dependent on the specific reaction conditions and methodologies employed. Dc magnetic susceptibility studies on , , and reveals strong antiferromagnetic exchange between the Cu(ii) centres in all siblings. We also present the 1D coordination polymer {[Cu(ii)(L4)]·H2O}n () comprising the pseudo macrocyclic ligand [[2-[(E)-(2-hydroxy-3-methoxy-phenyl)methyleneamino]benzoyl]amino]ethanimidate (L4H2), which is formed upon the incorporation of an MeCN unit at the hydroxamate group of precursor ligand L1H3.

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