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Dethe DH, Murhade GM, Ghosh S. FeCl3-Catalyzed Intramolecular Michael Reaction of Styrenes for the Synthesis of Highly Substituted Indenes. J Org Chem. 2015;80(16):8367-76doi: 10.1021/acs.joc.5b01071.
Dethe, D. H., Murhade, G. M., & Ghosh, S. (2015). FeCl3-Catalyzed Intramolecular Michael Reaction of Styrenes for the Synthesis of Highly Substituted Indenes. The Journal of organic chemistry, 80(16), 8367-76. https://doi.org/10.1021/acs.joc.5b01071
Dethe, Dattatraya H, et al. "FeCl3-Catalyzed Intramolecular Michael Reaction of Styrenes for the Synthesis of Highly Substituted Indenes." The Journal of organic chemistry vol. 80,16 (2015): 8367-76. doi: https://doi.org/10.1021/acs.joc.5b01071
Dethe DH, Murhade GM, Ghosh S. FeCl3-Catalyzed Intramolecular Michael Reaction of Styrenes for the Synthesis of Highly Substituted Indenes. J Org Chem. 2015 Aug 21;80(16):8367-76. doi: 10.1021/acs.joc.5b01071. Epub 2015 Jul 31. PMID: 26182950.
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J Org Chem. 2015 Aug 21;80(16):8367-76. doi: 10.1021/acs.joc.5b01071. Epub 2015 Jul 31.

FeCl3-Catalyzed Intramolecular Michael Reaction of Styrenes for the Synthesis of Highly Substituted Indenes.

The Journal of organic chemistry

Dattatraya H Dethe, Ganesh M Murhade, Sourav Ghosh

Affiliations

  1. Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India.

PMID: 26182950 DOI: 10.1021/acs.joc.5b01071

Abstract

An intramolecular FeCl3-catalyzed Michael addition reaction of styrene, a poor nucleophile, onto α,β-unsaturated ketones was developed for the synthesis of highly substituted indene derivatives. The method was further applied to the total synthesis of the sesquiterpene natural products (±)-jungianol and 1-epi-jungianol.

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