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Lichtenberg C, Viciu L, Vogt M, et al. Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster. Chem Commun (Camb). 2015;51(73):13890-3doi: 10.1039/c5cc04908c.
Lichtenberg, C., Viciu, L., Vogt, M., Rodríguez-Lugo, R. E., Adelhardt, M., Sutter, J., Khusniyarov, M. M., Meyer, K., de Bruin, B., Bill, E., & Grützmacher, H. (2015). Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster. Chemical communications (Cambridge, England), 51(73), 13890-3. https://doi.org/10.1039/c5cc04908c
Lichtenberg, C, et al. "Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster." Chemical communications (Cambridge, England) vol. 51,73 (2015): 13890-3. doi: https://doi.org/10.1039/c5cc04908c
Lichtenberg C, Viciu L, Vogt M, Rodríguez-Lugo RE, Adelhardt M, Sutter J, Khusniyarov MM, Meyer K, de Bruin B, Bill E, Grützmacher H. Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster. Chem Commun (Camb). 2015 Sep 21;51(73):13890-3. doi: 10.1039/c5cc04908c. PMID: 26221636.
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Chem Commun (Camb). 2015 Sep 21;51(73):13890-3. doi: 10.1039/c5cc04908c.

Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster.

Chemical communications (Cambridge, England)

C Lichtenberg, L Viciu, M Vogt, R E Rodríguez-Lugo, M Adelhardt, J Sutter, M M Khusniyarov, K Meyer, B de Bruin, E Bill, H Grützmacher

Affiliations

  1. Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093, Switzerland. [email protected] [email protected].

PMID: 26221636 DOI: 10.1039/c5cc04908c

Abstract

A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.

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