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Vasiloiu M, Gaertner P, Zirbs R, et al. Coordinating Chiral Ionic Liquids: Design, Synthesis, and Application in Asymmetric Transfer Hydrogenation under Aqueous Conditions. European J Org Chem. 2015;2015(11):2374-2381doi: 10.1002/ejoc.201403555.
Vasiloiu, M., Gaertner, P., Zirbs, R., & Bica, K. (2015). Coordinating Chiral Ionic Liquids: Design, Synthesis, and Application in Asymmetric Transfer Hydrogenation under Aqueous Conditions. European journal of organic chemistry, 2015(11), 2374-2381. https://doi.org/10.1002/ejoc.201403555
Vasiloiu, Maria, et al. "Coordinating Chiral Ionic Liquids: Design, Synthesis, and Application in Asymmetric Transfer Hydrogenation under Aqueous Conditions." European journal of organic chemistry vol. 2015,11 (2015): 2374-2381. doi: https://doi.org/10.1002/ejoc.201403555
Vasiloiu M, Gaertner P, Zirbs R, Bica K. Coordinating Chiral Ionic Liquids: Design, Synthesis, and Application in Asymmetric Transfer Hydrogenation under Aqueous Conditions. European J Org Chem. 2015 Apr;2015(11):2374-2381. doi: 10.1002/ejoc.201403555. Epub 2015 Feb 20. PMID: 26279638; PMCID: PMC4529664.
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European J Org Chem. 2015 Apr;2015(11):2374-2381. doi: 10.1002/ejoc.201403555. Epub 2015 Feb 20.

Coordinating Chiral Ionic Liquids: Design, Synthesis, and Application in Asymmetric Transfer Hydrogenation under Aqueous Conditions.

European journal of organic chemistry

Maria Vasiloiu, Peter Gaertner, Ronald Zirbs, Katharina Bica

Affiliations

  1. Institute of Applied Synthetic Chemistry, Vienna University of Technology Getreidemarkt 9/163, 1060 Vienna, Austria E-mail: [email protected] http://www.ias.tuwien.ac.at/home/
  2. Laboratory for Bioinspired Materials, Department of NanoBiotechnology, BOKU - University of Natural Resources and Life Sciences Vienna Muthgasse 11, 1190 Vienna, Austria.

PMID: 26279638 PMCID: PMC4529664 DOI: 10.1002/ejoc.201403555

Abstract

Hydrophilic coordinating chiral ionic liquids with an amino alcohol substructure were developed and efficiently applied to the asymmetric reduction of ketones. Their careful design and adaptability to the desired reaction conditions allow for these chiral ionic liquids to be used as the sole source of chirality in a ruthenium-catalyzed transfer hydrogenation reaction of aromatic ketones. When used in this reaction system, these chiral ionic liquids afforded excellent yields and high enantioselectivities.

Keywords: Asymmetric catalysis; Hydrogenation; Ionic liquids; Ketones; Ruthenium; Self-assembly

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