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Zhong DC, Wen YQ, Deng JH, et al. Uncovering the Role of Metal Catalysis in Tetrazole Formation by an In Situ Cycloaddition Reaction: An Experimental Approach. Angew Chem Int Ed Engl. 2015;54(40):11795-9doi: 10.1002/anie.201505118.
Zhong, D. C., Wen, Y. Q., Deng, J. H., Luo, X. Z., Gong, Y. N., & Lu, T. B. (2015). Uncovering the Role of Metal Catalysis in Tetrazole Formation by an In Situ Cycloaddition Reaction: An Experimental Approach. Angewandte Chemie (International ed. in English), 54(40), 11795-9. https://doi.org/10.1002/anie.201505118
Zhong, Di-Chang, et al. "Uncovering the Role of Metal Catalysis in Tetrazole Formation by an In Situ Cycloaddition Reaction: An Experimental Approach." Angewandte Chemie (International ed. in English) vol. 54,40 (2015): 11795-9. doi: https://doi.org/10.1002/anie.201505118
Zhong DC, Wen YQ, Deng JH, Luo XZ, Gong YN, Lu TB. Uncovering the Role of Metal Catalysis in Tetrazole Formation by an In Situ Cycloaddition Reaction: An Experimental Approach. Angew Chem Int Ed Engl. 2015 Sep 28;54(40):11795-9. doi: 10.1002/anie.201505118. Epub 2015 Aug 18. PMID: 26293313.
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Angew Chem Int Ed Engl. 2015 Sep 28;54(40):11795-9. doi: 10.1002/anie.201505118. Epub 2015 Aug 18.

Uncovering the Role of Metal Catalysis in Tetrazole Formation by an In Situ Cycloaddition Reaction: An Experimental Approach.

Angewandte Chemie (International ed. in English)

Di-Chang Zhong, Ya-Qiong Wen, Ji-Hua Deng, Xu-Zhong Luo, Yun-Nan Gong, Tong-Bu Lu

Affiliations

  1. School of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000 (P.R. China). [email protected].
  2. School of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000 (P.R. China).
  3. School of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000 (P.R. China). [email protected].
  4. School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275 (P.R. China). [email protected].

PMID: 26293313 DOI: 10.1002/anie.201505118

Abstract

Using an experimental approach, the role of metal catalysis has been investigated in the in situ cycloaddition reaction of nitrile with azide to form tetrazoles. It has been shown that metal catalysis serves to activate the cyano group in the nitrile reagent by a coordinative interaction.

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: cycloaddition; metal catalysis; reaction mechanisms; structure elucidation; tetrazoles

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