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Zhu JL, Li JH, Wang M, et al. Crystal structure of aqua-bis-[4-(methyl-sulfan-yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N')copper(II) monohydrate. Acta Crystallogr E Crystallogr Commun. 2015;71:980-2doi: 10.1107/S205698901501364X.
Zhu, J. L., Li, J. H., Wang, M., Jiang, G. M., & Jiang, G. Q. (2015). Crystal structure of aqua-bis-[4-(methyl-sulfan-yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N')copper(II) monohydrate. Acta crystallographica. Section E, Crystallographic communications, 71980-2. https://doi.org/10.1107/S205698901501364X
Zhu, Jin-Li, et al. "Crystal structure of aqua-bis-[4-(methyl-sulfan-yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N')copper(II) monohydrate." Acta crystallographica. Section E, Crystallographic communications vol. 71 (2015): 980-2. doi: https://doi.org/10.1107/S205698901501364X
Zhu JL, Li JH, Wang M, Jiang GM, Jiang GQ. Crystal structure of aqua-bis-[4-(methyl-sulfan-yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N')copper(II) monohydrate. Acta Crystallogr E Crystallogr Commun. 2015 Jul 29;71:980-2. doi: 10.1107/S205698901501364X. eCollection 2015 Aug 01. PMID: 26396770; PMCID: PMC4571371.
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Acta Crystallogr E Crystallogr Commun. 2015 Jul 29;71:980-2. doi: 10.1107/S205698901501364X. eCollection 2015 Aug 01.

Crystal structure of aqua-bis-[4-(methyl-sulfan-yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N')copper(II) monohydrate.

Acta crystallographica. Section E, Crystallographic communications

Jin-Li Zhu, Jian-Hua Li, Miao Wang, Guo-Min Jiang, Guo-Qing Jiang

Affiliations

  1. College of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, People's Republic of China.

PMID: 26396770 PMCID: PMC4571371 DOI: 10.1107/S205698901501364X

Abstract

In the title compound, [Cu(C8H7O2S)2(C12H8N2)(H2O)]·H2O, the central Cu(II) atom is five-coordinated in a slightly distorted square-pyramidal environment by two N atoms from a 1,10-phenanthroline ligand, one O atom from the carboxylate group of one 4-(methyl-sulfan-yl)benzoate anion and one water O atom in the equatorial plane while the apical position is occupied by the O atom of a carboxylate group of the second anion. In the crystal, a three-dimensional supra-molecular network is formed through weak inter-molecular C-H⋯O and C-H⋯S inter-actions and π-stacking between the 1,10-phenanthroline ligand and the aromatic rings of symmetry-related 4-(methyl-sulfan-yl)benzoate ligands.

Keywords: 1,10-phenanthroline; benzoate; copper(II) complex; crystal structure

References

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