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Chen H, Kaga A, Chiba S. anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(iii) reagents. Org Biomol Chem. 2015;14(24):5481-5doi: 10.1039/c5ob01854d.
Chen, H., Kaga, A., & Chiba, S. (2016). anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(iii) reagents. Organic & biomolecular chemistry, 14(24), 5481-5. https://doi.org/10.1039/c5ob01854d
Chen, Hui, et al. "anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(iii) reagents." Organic & biomolecular chemistry vol. 14,24 (2016): 5481-5. doi: https://doi.org/10.1039/c5ob01854d
Chen H, Kaga A, Chiba S. anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(iii) reagents. Org Biomol Chem. 2016 Jun 28;14(24):5481-5. doi: 10.1039/c5ob01854d. Epub 2015 Oct 01. PMID: 26426571.
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Org Biomol Chem. 2016 Jun 28;14(24):5481-5. doi: 10.1039/c5ob01854d. Epub 2015 Oct 01.

anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(iii) reagents.

Organic & biomolecular chemistry

Hui Chen, Atsushi Kaga, Shunsuke Chiba

Affiliations

  1. Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore. [email protected].

PMID: 26426571 DOI: 10.1039/c5ob01854d

Abstract

anti-Selective aminofluorination of alkenes with amidines was enabled by hypervalent iodine(iii) reagents, affording 4-fluoroalkyl-2-imidazolines. Further reductive ring-opening of the 2-imidazoline moiety could deliver highly functionalized 3-fluoropropane-1,2-diamine derivatives.

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