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Iqbal D, Sarfraz A, Stratmann M, et al. Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front. Chem Commun (Camb). 2015;51(89):16041-4doi: 10.1039/c5cc06468f.
Iqbal, D., Sarfraz, A., Stratmann, M., & Erbe, A. (2015). Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front. Chemical communications (Cambridge, England), 51(89), 16041-4. https://doi.org/10.1039/c5cc06468f
Iqbal, Danish, et al. "Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front." Chemical communications (Cambridge, England) vol. 51,89 (2015): 16041-4. doi: https://doi.org/10.1039/c5cc06468f
Iqbal D, Sarfraz A, Stratmann M, Erbe A. Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front. Chem Commun (Camb). 2015 Nov 18;51(89):16041-4. doi: 10.1039/c5cc06468f. PMID: 26344142.
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Chem Commun (Camb). 2015 Nov 18;51(89):16041-4. doi: 10.1039/c5cc06468f.

Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front.

Chemical communications (Cambridge, England)

Danish Iqbal, Adnan Sarfraz, Martin Stratmann, Andreas Erbe

Affiliations

  1. Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Str. 1, 40237 Düsseldorf, Germany. [email protected] [email protected].

PMID: 26344142 DOI: 10.1039/c5cc06468f

Abstract

After passage of a delamination front at a polymer/zinc interface, pH oscillations and oscillations in the quantity of corrosion products are observed. The reason for these oscillations is the low quantity of water in the confined reaction volume, water consumption by oxygen reduction, and water regeneration after precipitation of ZnO.

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