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Inorg Chem. 2015 Oct 05;54(19):9387-9. doi: 10.1021/acs.inorgchem.5b01569. Epub 2015 Sep 16.

Solvent-free synthesis of crystalline metal phosphate oxalates with a (4,6)-connected fsh topology.

Inorganic chemistry

Lindong Luan, Jing Li, Cheng Chen, Zhien Lin, Hui Huang

Affiliations

  1. College of Chemistry, Sichuan University , Chengdu 610064, People's Republic of China.
  2. School of Chemistry, Beijing Institute of Technology , Beijing 100081, People's Republic of China.

PMID: 26375381 DOI: 10.1021/acs.inorgchem.5b01569

Abstract

Two new organically templated manganese phosphate oxalates were synthesized under solvent-free conditions. They have different three-dimensional structures with a (4,6)-connected fsh topology. It is interesting that the amine molecules can reverse the structure-building roles of the metal phosphate skeleton and metal oxalate substructure for formation of their fsh-type frameworks.

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