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Barth S, Biegger F, Puchberger M. Synthesis and characterisation of thioether functionalised gallium and indium alkoxides. Dalton Trans. 2015;44(37):16439-45doi: 10.1039/c5dt02777b.
Barth, S., Biegger, F., & Puchberger, M. (2015). Synthesis and characterisation of thioether functionalised gallium and indium alkoxides. Dalton transactions (Cambridge, England : 2003), 44(37), 16439-45. https://doi.org/10.1039/c5dt02777b
Barth, Sven, et al. "Synthesis and characterisation of thioether functionalised gallium and indium alkoxides." Dalton transactions (Cambridge, England : 2003) vol. 44,37 (2015): 16439-45. doi: https://doi.org/10.1039/c5dt02777b
Barth S, Biegger F, Puchberger M. Synthesis and characterisation of thioether functionalised gallium and indium alkoxides. Dalton Trans. 2015 Oct 07;44(37):16439-45. doi: 10.1039/c5dt02777b. PMID: 26313352.
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Dalton Trans. 2015 Oct 07;44(37):16439-45. doi: 10.1039/c5dt02777b.

Synthesis and characterisation of thioether functionalised gallium and indium alkoxides.

Dalton transactions (Cambridge, England : 2003)

Sven Barth, Felix Biegger, Michael Puchberger

Affiliations

  1. Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9/BC/02, 1060 Vienna, Austria. [email protected].

PMID: 26313352 DOI: 10.1039/c5dt02777b

Abstract

This paper provides evidence of formerly unknown thioether coordination in metal alkoxides. The thioether functionalised alkanols serving as alcoholate ligands have been prepared by a generic route. The gallium and indium alkoxides provide the first evidence for sulphur coordination in the liquid and solid state in metal alkoxide derivatives. The presence of amines suppresses the coordination of thioether moieties leading to a well-known bonding mode in aminoalcoholates.

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