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ACS Appl Mater Interfaces. 2015 Sep 30;7(38):21005-9. doi: 10.1021/acsami.5b05881. Epub 2015 Sep 21.

Carbon Nanotubes as Reinforcement of Cellulose Liquid Crystalline Responsive Networks.

ACS applied materials & interfaces

Coro Echeverria, Luis E Aguirre, Esther G Merino, Pedro L Almeida, Maria H Godinho

Affiliations

  1. I3N-CENIMAT, and Departamento de Ciência dos Materiais, Faculdade de Ciências e Tecnologia, Universidade NOVA de Lisboa , 2829-516 Caparica, Portugal.
  2. Soft Matter and Molecular Biophysics Group. Department of Applied Physics, University of Santiago de Compostela , E-15782, 15782 Santiago de Compostela, España.
  3. Area Departamental de Física, Instituto Superior de Engenharia de Lisboa , ISEL/IPL, R. Conselheiro Emídio Navarro, 1, 1959-007 Lisboa, Portugal.

PMID: 26378467 DOI: 10.1021/acsami.5b05881

Abstract

The incorporation of small amount of highly anisotropic nanoparticles into liquid crystalline hydroxypropylcellulose (LC-HPC) matrix improves its response when is exposed to humidity gradients due to an anisotropic increment of order in the structure. Dispersed nanoparticles give rise to faster order/disorder transitions when exposed to moisture as it is qualitatively observed and quantified by stress-time measurements. The presence of carbon nanotubes derives in a improvement of the mechanical properties of LC-HPC thin films.

Keywords: actuator; carbon nanotubes; cellulose derivative; humidity-responsive; polymer liquid crystal; soft motor

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