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Heinl S, Peresypkina E, Sutter J, et al. Giant Spherical Cluster with I-C140 Fullerene Topology. Angew Chem Int Ed Engl. 2015;54(45):13431-5doi: 10.1002/anie.201505516.
Heinl, S., Peresypkina, E., Sutter, J., & Scheer, M. (2015). Giant Spherical Cluster with I-C140 Fullerene Topology. Angewandte Chemie (International ed. in English), 54(45), 13431-5. https://doi.org/10.1002/anie.201505516
Heinl, Sebastian, et al. "Giant Spherical Cluster with I-C140 Fullerene Topology." Angewandte Chemie (International ed. in English) vol. 54,45 (2015): 13431-5. doi: https://doi.org/10.1002/anie.201505516
Heinl S, Peresypkina E, Sutter J, Scheer M. Giant Spherical Cluster with I-C140 Fullerene Topology. Angew Chem Int Ed Engl. 2015 Nov 02;54(45):13431-5. doi: 10.1002/anie.201505516. Epub 2015 Sep 28. PMID: 26411255; PMCID: PMC4691335.
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Angew Chem Int Ed Engl. 2015 Nov 02;54(45):13431-5. doi: 10.1002/anie.201505516. Epub 2015 Sep 28.

Giant Spherical Cluster with I-C140 Fullerene Topology.

Angewandte Chemie (International ed. in English)

Sebastian Heinl, Eugenia Peresypkina, Jörg Sutter, Manfred Scheer

Affiliations

  1. Institute of Inorganic Chemistry, University of Regensburg, Universitätsstrasse 31, 93040 Regensburg (Germany).
  2. Nikolaev Institute of Inorganic Chemistry, SB RAS, Ak. Lavrentiev prosp. 3, 630090 Novosibirsk (Russia).
  3. Department of Chemistry and Pharmacy, Inorganic Chemistry, FAU Erlangen-Nürnberg (FAU), Egerlandstrasse 1, 91058 Erlangen (Germany).
  4. Institute of Inorganic Chemistry, University of Regensburg, Universitätsstrasse 31, 93040 Regensburg (Germany). [email protected].

PMID: 26411255 PMCID: PMC4691335 DOI: 10.1002/anie.201505516

Abstract

We report on an effective cluster expansion of CuBr-linked aggregates by the increase of the steric bulk of the Cp(R) ligand in the pentatopic molecules [Cp(R)Fe(η(5)-P5)]. Using [Cp(BIG)Fe(η(5)-P5)] (Cp(BIG)=C5(4-nBuC6H4)5), the novel multishell aggregate [{Cp(BIG)Fe(η(5:2:1:1:1:1:1)-P5)}12(CuBr)92] is obtained. It shows topological analogy to the theoretically predicted I-C140 fullerene molecule. The spherical cluster was comprehensively characterized by various methods in solution and in the solid state.

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: C140 fullerene; CpBIG; giant clusters; pentaphosphaferrocene; supramolecular chemistry

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