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Crawford JM, Shelton KE, Reeves EK, et al. Nickel-Catalyzed Decarboxylative Arylation of Azoles with Perfluoro- and Nitrobenzoates. Org Chem Front. 2015;2(6):726-729doi: 10.1039/C5QO00040H.
Crawford, J. M., Shelton, K. E., Reeves, E. K., Sadarananda, B. K., & Kalyani, D. (2015). Nickel-Catalyzed Decarboxylative Arylation of Azoles with Perfluoro- and Nitrobenzoates. Organic chemistry frontiers : an international journal of organic chemistry, 2(6), 726-729. https://doi.org/10.1039/C5QO00040H
Crawford, Jennifer M, et al. "Nickel-Catalyzed Decarboxylative Arylation of Azoles with Perfluoro- and Nitrobenzoates." Organic chemistry frontiers : an international journal of organic chemistry vol. 2,6 (2015): 726-729. doi: https://doi.org/10.1039/C5QO00040H
Crawford JM, Shelton KE, Reeves EK, Sadarananda BK, Kalyani D. Nickel-Catalyzed Decarboxylative Arylation of Azoles with Perfluoro- and Nitrobenzoates. Org Chem Front. 2015 Jun 01;2(6):726-729. doi: 10.1039/C5QO00040H. Epub 2015 May 12. PMID: 26478819; PMCID: PMC4606873.
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Org Chem Front. 2015 Jun 01;2(6):726-729. doi: 10.1039/C5QO00040H. Epub 2015 May 12.

Nickel-Catalyzed Decarboxylative Arylation of Azoles with Perfluoro- and Nitrobenzoates.

Organic chemistry frontiers : an international journal of organic chemistry

Jennifer M Crawford, Kyle E Shelton, Emily K Reeves, Bryce K Sadarananda, Dipannita Kalyani

Affiliations

  1. St. Olaf College, 1520 St. Olaf Ave., Northfield MN 55057.

PMID: 26478819 PMCID: PMC4606873 DOI: 10.1039/C5QO00040H

Abstract

This manuscript describes a Ni-catalyzed method for the direct arylation of azoles using benzoates. Perfluorophenyl and 2-nitrobenzoates participate in these reactions to afford the corresponding products in modest to good yields. The efficiency of the arylations with perfluorobenzoates is highly dependent on both the degree and position of fluorine atoms in the benzoates.

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