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Pagano JK, Dorhout JM, Waterman R, et al. Phenylsilane as a safe, versatile alternative to hydrogen for the synthesis of actinide hydrides. Chem Commun (Camb). 2015;51(98):17379-81doi: 10.1039/c5cc06856h.
Pagano, J. K., Dorhout, J. M., Waterman, R., Czerwinski, K. R., & Kiplinger, J. L. (2015). Phenylsilane as a safe, versatile alternative to hydrogen for the synthesis of actinide hydrides. Chemical communications (Cambridge, England), 51(98), 17379-81. https://doi.org/10.1039/c5cc06856h
Pagano, Justin K, et al. "Phenylsilane as a safe, versatile alternative to hydrogen for the synthesis of actinide hydrides." Chemical communications (Cambridge, England) vol. 51,98 (2015): 17379-81. doi: https://doi.org/10.1039/c5cc06856h
Pagano JK, Dorhout JM, Waterman R, Czerwinski KR, Kiplinger JL. Phenylsilane as a safe, versatile alternative to hydrogen for the synthesis of actinide hydrides. Chem Commun (Camb). 2015 Dec 21;51(98):17379-81. doi: 10.1039/c5cc06856h. Epub 2015 Oct 22. PMID: 26490094.
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Chem Commun (Camb). 2015 Dec 21;51(98):17379-81. doi: 10.1039/c5cc06856h. Epub 2015 Oct 22.

Phenylsilane as a safe, versatile alternative to hydrogen for the synthesis of actinide hydrides.

Chemical communications (Cambridge, England)

Justin K Pagano, Jacquelyn M Dorhout, Rory Waterman, Kenneth R Czerwinski, Jaqueline L Kiplinger

Affiliations

  1. Chemistry Division, Los Alamos National Laboratory, Mail Stop J514, Los Alamos, NM 87545, USA. [email protected].

PMID: 26490094 DOI: 10.1039/c5cc06856h

Abstract

The thorium and uranium dihydride dimer complexes [(C5Me5)2An(H)(μ-H)]2 (An = Th, U) have been easily prepared using phenylsilane, which is an efficient and safer alternative to hydrogen gas. The synthetic utility of this new hydriding method has been demonstrated by the preparation of a variety of organometallic complexes, including, for the first time, (C5Me5)2U(SMe)2, (C5Me5)2Th(C4Ph4), (C5Me5)2U(C4Ph4), (C5Me5)2ThS5, and (C5Me5)2U(bipy) using [(C5Me5)2An(H)(μ-H)]2 (An = Th, U) as multi-electron reductants.

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