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Scott DJ, Simmons TR, Lawrence EJ, et al. Facile Protocol for Water-Tolerant "Frustrated Lewis Pair"-Catalyzed Hydrogenation. ACS Catal. 2015;5(9):5540-5544doi: 10.1021/acscatal.5b01417.
Scott, D. J., Simmons, T. R., Lawrence, E. J., Wildgoose, G. G., Fuchter, M. J., & Ashley, A. E. (2015). Facile Protocol for Water-Tolerant "Frustrated Lewis Pair"-Catalyzed Hydrogenation. ACS catalysis, 5(9), 5540-5544. https://doi.org/10.1021/acscatal.5b01417
Scott, Daniel J, et al. "Facile Protocol for Water-Tolerant "Frustrated Lewis Pair"-Catalyzed Hydrogenation." ACS catalysis vol. 5,9 (2015): 5540-5544. doi: https://doi.org/10.1021/acscatal.5b01417
Scott DJ, Simmons TR, Lawrence EJ, Wildgoose GG, Fuchter MJ, Ashley AE. Facile Protocol for Water-Tolerant "Frustrated Lewis Pair"-Catalyzed Hydrogenation. ACS Catal. 2015 Sep 04;5(9):5540-5544. doi: 10.1021/acscatal.5b01417. Epub 2015 Aug 17. PMID: 26523238; PMCID: PMC4613738.
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ACS Catal. 2015 Sep 04;5(9):5540-5544. doi: 10.1021/acscatal.5b01417. Epub 2015 Aug 17.

Facile Protocol for Water-Tolerant "Frustrated Lewis Pair"-Catalyzed Hydrogenation.

ACS catalysis

Daniel J Scott, Trevor R Simmons, Elliot J Lawrence, Gregory G Wildgoose, Matthew J Fuchter, Andrew E Ashley

Affiliations

  1. Department of Chemistry, Imperial College London , London, SW7 2AZ, United Kingdom.
  2. Energy Materials Laboratory, School of Chemistry, University of East Anglia , Norwich Research Park, Norwich, NR4 7TJ, United Kingdom.

PMID: 26523238 PMCID: PMC4613738 DOI: 10.1021/acscatal.5b01417

Abstract

Despite rapid advances in the field of metal-free, "frustrated Lewis pair" (FLP)-catalyzed hydrogenation, the need for strictly anhydrous reaction conditions has hampered wide-scale uptake of this methodology. Herein, we report that, despite the generally perceived moisture sensitivity of FLPs, 1,4-dioxane solutions of B(C

Keywords: catalytic hydrogenation; metal-free; solvent effects; water tolerance; “frustrated Lewis pairs”

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