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Dubois F, Derouiche Y, Leblond JM, et al. Compensated Arrhenius formalism applied to a conductivity study in poly(propylene glycol) diacrylate monomers. Phys Rev E Stat Nonlin Soft Matter Phys. 2015;92(3):032601doi: 10.1103/PhysRevE.92.032601.
Dubois, F., Derouiche, Y., Leblond, J. M., Maschke, U., & Douali, R. (2015). Compensated Arrhenius formalism applied to a conductivity study in poly(propylene glycol) diacrylate monomers. Physical review. E, Statistical, nonlinear, and soft matter physics, 92(3), 032601. https://doi.org/10.1103/PhysRevE.92.032601
Dubois, F, et al. "Compensated Arrhenius formalism applied to a conductivity study in poly(propylene glycol) diacrylate monomers." Physical review. E, Statistical, nonlinear, and soft matter physics vol. 92,3 (2015): 032601. doi: https://doi.org/10.1103/PhysRevE.92.032601
Dubois F, Derouiche Y, Leblond JM, Maschke U, Douali R. Compensated Arrhenius formalism applied to a conductivity study in poly(propylene glycol) diacrylate monomers. Phys Rev E Stat Nonlin Soft Matter Phys. 2015 Sep;92(3):032601. doi: 10.1103/PhysRevE.92.032601. Epub 2015 Sep 04. PMID: 26465489.
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Phys Rev E Stat Nonlin Soft Matter Phys. 2015 Sep;92(3):032601. doi: 10.1103/PhysRevE.92.032601. Epub 2015 Sep 04.

Compensated Arrhenius formalism applied to a conductivity study in poly(propylene glycol) diacrylate monomers.

Physical review. E, Statistical, nonlinear, and soft matter physics

F Dubois, Y Derouiche, J M Leblond, U Maschke, R Douali

Affiliations

  1. Unité de Dynamique et Structure des Matériaux Moléculaires (UDSMM), Université du Littoral Côte d'Opale, F-62228 Calais, France.
  2. Unité de Dynamique et Structure des Matériaux Moléculaires (UDSMM), Université du Littoral Côte d'Opale, F-62228 Calais, France; Unité Matériaux Et Transformations (UMET), Université de Lille 1 - Sciences et Technologies, F-59655 Villeneuve d'Ascq Cedex, France; and Laboratoire de Dispositifs Micro-ondes et Matériaux pour les Energies Renouvelables (DIMMER), Université Ziane Achour, 17000 Djelfa, Algeria.
  3. Unité Matériaux Et Transformations (UMET), Université de Lille 1 - Sciences et Technologies, F-59655 Villeneuve d'Ascq Cedex, France.

PMID: 26465489 DOI: 10.1103/PhysRevE.92.032601

Abstract

The temperature dependence of the ionic conductivity is studied in a series of poly(propylene glycol) diacrylate monomers. The experimental data are analyzed by means of the approach recently proposed by Petrowsky et al. [J. Phys. Chem. B. 113, 5996 (2009)10.1021/jp810095g]. This so-called compensated Arrhenius formalism (CAF) approach takes into account the influence of the dielectric permittivity on the exponential prefactor in the classical Arrhenius equation. The experimental data presented in this paper show a good agreement with the CAF; this means that the exponential prefactor is principally dielectric permittivity dependent. The compensated data revealed two conduction processes with different activation energies; they correspond to low and high temperature ranges, respectively.

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