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Ma D, Yan Y, Ji H, et al. Photocatalytic activation of pyridine for addition reactions: an unconventional reaction feature between a photo-induced hole and electron on TiO2. Chem Commun (Camb). 2015;51(98):17451-4doi: 10.1039/c5cc07123b.
Ma, D., Yan, Y., Ji, H., Chen, C., & Zhao, J. (2015). Photocatalytic activation of pyridine for addition reactions: an unconventional reaction feature between a photo-induced hole and electron on TiO2. Chemical communications (Cambridge, England), 51(98), 17451-4. https://doi.org/10.1039/c5cc07123b
Ma, Dongge, et al. "Photocatalytic activation of pyridine for addition reactions: an unconventional reaction feature between a photo-induced hole and electron on TiO2." Chemical communications (Cambridge, England) vol. 51,98 (2015): 17451-4. doi: https://doi.org/10.1039/c5cc07123b
Ma D, Yan Y, Ji H, Chen C, Zhao J. Photocatalytic activation of pyridine for addition reactions: an unconventional reaction feature between a photo-induced hole and electron on TiO2. Chem Commun (Camb). 2015 Dec 21;51(98):17451-4. doi: 10.1039/c5cc07123b. Epub 2015 Oct 15. PMID: 26468512.
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Chem Commun (Camb). 2015 Dec 21;51(98):17451-4. doi: 10.1039/c5cc07123b. Epub 2015 Oct 15.

Photocatalytic activation of pyridine for addition reactions: an unconventional reaction feature between a photo-induced hole and electron on TiO2.

Chemical communications (Cambridge, England)

Dongge Ma, Yan Yan, Hongwei Ji, Chuncheng Chen, Jincai Zhao

Affiliations

  1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institution Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. [email protected] [email protected].

PMID: 26468512 DOI: 10.1039/c5cc07123b

Abstract

TiO2 photocatalysis can be performed for the addition of pyridines to vinylarenes in an anti-Markovnikov manner. Seven examples with considerable yields (56-91%) and selectivity were demonstrated. A comparative survey of the involved process through ESR revealed a novel concerted two electron transfer pathway for these photocatalytic bimolecular addition reactions.

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