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Anari EH, Romano M, Teh WX, et al. Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids. Chem Commun (Camb). 2016;52(4):745-8doi: 10.1039/c5cc05889a.
Anari, E. H., Romano, M., Teh, W. X., Black, J. J., Jiang, E., Chen, J., To, T. Q., Panchompoo, J., & Aldous, L. (2016). Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids. Chemical communications (Cambridge, England), 52(4), 745-8. https://doi.org/10.1039/c5cc05889a
Anari, E H B, et al. "Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids." Chemical communications (Cambridge, England) vol. 52,4 (2016): 745-8. doi: https://doi.org/10.1039/c5cc05889a
Anari EH, Romano M, Teh WX, Black JJ, Jiang E, Chen J, To TQ, Panchompoo J, Aldous L. Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids. Chem Commun (Camb). 2016 Jan 14;52(4):745-8. doi: 10.1039/c5cc05889a. PMID: 26563939.
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Chem Commun (Camb). 2016 Jan 14;52(4):745-8. doi: 10.1039/c5cc05889a.

Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids.

Chemical communications (Cambridge, England)

E H B Anari, M Romano, W X Teh, J J Black, E Jiang, J Chen, T Q To, J Panchompoo, L Aldous

Affiliations

  1. School of Chemistry, UNSW Australia, Sydney, NSW 2052, Australia. [email protected].
  2. Intelligent Polymer Research Institute, Innovation Campus, University of Wollongong, Wollongong, NSW 2522, Australia.

PMID: 26563939 DOI: 10.1039/c5cc05889a

Abstract

Combining ferrocene and iodine results in enhanced thermoelectrochemical (or thermogalvanic) waste heat harvesting abilities, for both the Seebeck coefficient and the overall power output. All systems displayed a mixture of ferrocene, ferrocenium, iodine and triiodide. The observed enhancement correlates with lower electron-density on the ferrocene; the synergistic improvement observed for mixtures of substituted ferrocenes and iodine is attributed to the formation of charge-transfer complexes. Combining dibutanoylferrocene and iodine resulted in the highest Seebeck coefficient of 1.67 mV K(-1).

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