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Biswas S, Chakrabarti A, Chateauminois A, et al. Soft Lithography Using Nectar Droplets. Langmuir. 2015;31(48):13155-64doi: 10.1021/acs.langmuir.5b03829.
Biswas, S., Chakrabarti, A., Chateauminois, A., Wandersman, E., Prevost, A. M., & Chaudhury, M. K. (2015). Soft Lithography Using Nectar Droplets. Langmuir : the ACS journal of surfaces and colloids, 31(48), 13155-64. https://doi.org/10.1021/acs.langmuir.5b03829
Biswas, Saheli, et al. "Soft Lithography Using Nectar Droplets." Langmuir : the ACS journal of surfaces and colloids vol. 31,48 (2015): 13155-64. doi: https://doi.org/10.1021/acs.langmuir.5b03829
Biswas S, Chakrabarti A, Chateauminois A, Wandersman E, Prevost AM, Chaudhury MK. Soft Lithography Using Nectar Droplets. Langmuir. 2015 Dec 08;31(48):13155-64. doi: 10.1021/acs.langmuir.5b03829. Epub 2015 Nov 25. PMID: 26563988.
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Langmuir. 2015 Dec 08;31(48):13155-64. doi: 10.1021/acs.langmuir.5b03829. Epub 2015 Nov 25.

Soft Lithography Using Nectar Droplets.

Langmuir : the ACS journal of surfaces and colloids

Saheli Biswas, Aditi Chakrabarti, Antoine Chateauminois, Elie Wandersman, Alexis M Prevost, Manoj K Chaudhury

Affiliations

  1. Department of Chemical and Biomolecular Engineering, Lehigh University , Bethlehem, Pennsylvania 18015, United States.
  2. Soft Matter Science and Engineering Laboratory (SIMM), CNRS/UPMC Univ Paris 6, UMR 7615, ESPCI, F-75005 Paris, France.
  3. CNRS, Sorbonne Universités, UPMC Univ Paris 06, UMR 8237, Laboratoire Jean Perrin (LJP), F-75005, Paris, France.

PMID: 26563988 DOI: 10.1021/acs.langmuir.5b03829

Abstract

In spite of significant advances in replication technologies, methods to produce well-defined three-dimensional structures are still at its infancy. Such a limitation would be evident if we were to produce a large array of simple and, especially, compound convex lenses, also guaranteeing that their surfaces would be molecularly smooth. Here, we report a novel method to produce such structures by cloning the 3D shape of nectar drops, found widely in nature, using conventional soft lithography.The elementary process involves transfer of a thin patch of the sugar solution coated on a glass slide onto a hydrophobic substrate on which this patch evolves into a microdroplet. Upon the absorption of water vapor, such a microdroplet grows linearly with time, and its final size can be controlled by varying its exposure time to water vapor. At any stage of the evolution of the size of the drop, its shape can be cloned onto a soft elastomer by following the well-known methods of molding and cross-linking the same. A unique new science that emerges in our attempt to understand the transfer of the sugar patch and its evolution to a spherical drop is the elucidation of the mechanics underlying the contact of a deformable sphere against a solid support intervening a thin liquid film. A unique aspect of this work is to demonstrate that higher level structures can also be generated by transferring even smaller nucleation sites on the surface of the primary lenses and then allowing them to grow by absorption of water vapor. What results at the end is either a well-controlled distribution of smooth hemispherical lenses or compound structures that could have potential applications in the fundamental studies of contact mechanics, wettability, and even in optics.

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