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Angew Chem Int Ed Engl. 2015 Dec 14;54(51):15368-73. doi: 10.1002/anie.201507503. Epub 2015 Oct 27.

Thermally Tunable Hydrogels Displaying Angle-Independent Structural Colors.

Angewandte Chemie (International ed. in English)

Yumiko Ohtsuka, Takahiro Seki, Yukikazu Takeoka

Affiliations

  1. Department of Molecular Design and Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603 (Japan).
  2. Department of Molecular Design and Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603 (Japan). [email protected].

PMID: 26503915 PMCID: PMC4736687 DOI: 10.1002/anie.201507503

Abstract

We report the preparation of thermally tunable hydrogels displaying angle-independent structural colors. The porous structures were formed with short-range order using colloidal amorphous array templates and a small amount of carbon black (CB). The resultant porous hydrogels prepared using colloidal amorphous arrays without CB appeared white, whereas the hydrogels with CB revealed bright structural colors. The brightly colored hydrogels rapidly changed hues in a reversible manner, and the hues varied widely depending on the water temperature. Moreover, the structural colors were angle-independent under diffusive lighting because of the isotropic nanostructure generated from the colloidal amorphous arrays.

© 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.

Keywords: amorphous arrays; colloids; hydrogels; polymers; structural colors

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