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Vlaisavljevich B, Andrews L, Wang X, et al. Detection and Electronic Structure of Naked Actinide Complexes: Rhombic-Ring (AnN)2 Molecules Stabilized by Delocalized π-Bonding. J Am Chem Soc. 2016;138(3):893-905doi: 10.1021/jacs.5b10458.
Vlaisavljevich, B., Andrews, L., Wang, X., Gong, Y., Kushto, G. P., & Bursten, B. E. (2016). Detection and Electronic Structure of Naked Actinide Complexes: Rhombic-Ring (AnN)2 Molecules Stabilized by Delocalized π-Bonding. Journal of the American Chemical Society, 138(3), 893-905. https://doi.org/10.1021/jacs.5b10458
Vlaisavljevich, Bess, et al. "Detection and Electronic Structure of Naked Actinide Complexes: Rhombic-Ring (AnN)2 Molecules Stabilized by Delocalized π-Bonding." Journal of the American Chemical Society vol. 138,3 (2016): 893-905. doi: https://doi.org/10.1021/jacs.5b10458
Vlaisavljevich B, Andrews L, Wang X, Gong Y, Kushto GP, Bursten BE. Detection and Electronic Structure of Naked Actinide Complexes: Rhombic-Ring (AnN)2 Molecules Stabilized by Delocalized π-Bonding. J Am Chem Soc. 2016 Jan 27;138(3):893-905. doi: 10.1021/jacs.5b10458. Epub 2016 Jan 15. PMID: 26645301.
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J Am Chem Soc. 2016 Jan 27;138(3):893-905. doi: 10.1021/jacs.5b10458. Epub 2016 Jan 15.

Detection and Electronic Structure of Naked Actinide Complexes: Rhombic-Ring (AnN)2 Molecules Stabilized by Delocalized π-Bonding.

Journal of the American Chemical Society

Bess Vlaisavljevich, Lester Andrews, Xuefeng Wang, Yu Gong, Gary P Kushto, Bruce E Bursten

Affiliations

  1. Department of Chemistry, University of Minnesota and Supercomputing Institute , 207 Pleasant St. SE, Minneapolis, Minnesota 55455-0431, United States.
  2. Department of Chemical and Biomolecular Engineering, University of California , Berkeley, California 94720, United States.
  3. Department of Chemistry, University of Virginia , P.O. Box 400319, Charlottesville, Virginia 22904-4319, United States.
  4. Department of Chemistry, Tongji University , Shanghai 200092, China.
  5. United States Naval Research Laboratory , 4555 Overlook Ave SW, Washington, DC 20375, United States.
  6. Department of Chemistry and Biochemistry, Worcester Polytechnic Institute , Worcester, Massachusetts 01609-2280, United States.

PMID: 26645301 DOI: 10.1021/jacs.5b10458

Abstract

The major products of the reaction of laser ablated and excited U atoms and N2 are the linear N≡U≡N dinitride molecule, isoelectronic with the uranyl dication, and the diatomic nitride U≡N. These molecules form novel cyclic dimers, (UN)2 and (NUN)2, with complex electronic structures, in matrix isolation experiments, which increase on UV photolysis. In addition, (NUN)2 increases at the expense of (UN)2 upon warming the codeposited matrix samples into the 20-40 K range as attested by additional nitrogen and argon matrix infrared spectra recorded after cooling the samples back to 4 or 7 K. These molecules are identified through matrix infrared spectra with nitrogen isotopic substitution and by comparing the observed matrix frequencies with those from electronic structure calculations. The dimerization is strong (theory predicts the dimer to be on the order of 100 kcal/mol more stable than the monomers), since the ground state involves 12 bonding electrons, 8 in the σ-system, and 4 in the delocalized π-system. This delocalized π bonding is present in the U, Th, La, and Hf analogues further demonstrating the interesting interplay between the 5f and 6d orbitals in actinide chemistry. The (UN)2(+) cation is also observed in solid argon, and calculations indicate that the bonding in the ring is preserved. On the other hand, the NUN dimer is of lower C2h symmetry, and the initial NUN molecules are recognizable in this more weakly bonded (ΔE = -64 kcal/mol) structure. The NThN molecules bind more strongly in the (NThN)2 dimer than the NUN molecules in (NUN)2 since NUN itself is more stable than NThN.

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