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Chem Commun (Camb). 2016 Jan 21;52(6):1282-5. doi: 10.1039/c5cc07874a.

The first organically templated open-framework metal-sulfites with layered and three-dimensional diamondoid structures.

Chemical communications (Cambridge, England)

Ranjay K Tiwari, Jitendra Kumar, J N Behera

Affiliations

  1. School of Chemical Sciences, National Institute of Science Education and Research (NISER), Bhubaneswar 751005, India. [email protected].

PMID: 26615884 DOI: 10.1039/c5cc07874a

Abstract

The crystallographic signatures and characterization data of two novel organically templated open-framework zinc-sulfites (NH3CH2CH2NH3)[Zn3(SO3)4], 1, and (CN3H6)2[Zn(SO3)2], 2, are reported for the first time, synthesized under hydrothermal conditions using different amines, namely, ethylenediamine and guanidine, to generate 2D (for 1) and 3D (for 2) assemblies with 4-, 6-, 8- and 12-membered rings.

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