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Patra T, Nandi S, Sahoo SK, et al. Copper mediated decarboxylative direct C-H arylation of heteroarenes with benzoic acids. Chem Commun (Camb). 2016;52(7):1432-5doi: 10.1039/c5cc08367b.
Patra, T., Nandi, S., Sahoo, S. K., & Maiti, D. (2016). Copper mediated decarboxylative direct C-H arylation of heteroarenes with benzoic acids. Chemical communications (Cambridge, England), 52(7), 1432-5. https://doi.org/10.1039/c5cc08367b
Patra, Tuhin, et al. "Copper mediated decarboxylative direct C-H arylation of heteroarenes with benzoic acids." Chemical communications (Cambridge, England) vol. 52,7 (2016): 1432-5. doi: https://doi.org/10.1039/c5cc08367b
Patra T, Nandi S, Sahoo SK, Maiti D. Copper mediated decarboxylative direct C-H arylation of heteroarenes with benzoic acids. Chem Commun (Camb). 2016 Jan 25;52(7):1432-5. doi: 10.1039/c5cc08367b. PMID: 26647115.
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Chem Commun (Camb). 2016 Jan 25;52(7):1432-5. doi: 10.1039/c5cc08367b.

Copper mediated decarboxylative direct C-H arylation of heteroarenes with benzoic acids.

Chemical communications (Cambridge, England)

Tuhin Patra, Sudip Nandi, Santosh K Sahoo, Debabrata Maiti

Affiliations

  1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400076, India. [email protected].

PMID: 26647115 DOI: 10.1039/c5cc08367b

Abstract

Decarboxylative coupling reactions to date require a stoichiometric oxidant (such as copper and silver salts) for decarboxylation purposes along with a metal catalyst (e.g. palladium) for cross-coupling. In this communication, an economic and sustainable approach by using a simple copper salt was developed in the presence of molecular oxygen as the sole oxidant. A wide range of 5-membered heteroarenes undergo aryl-heteroaryl cross-coupling with electron deficient aryl carboxylic acids.

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