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Science. 2016 Jan 01;351(6268):58-62. doi: 10.1126/science.aad2688.

Additive manufacturing of polymer-derived ceramics.

Science (New York, N.Y.)

Zak C Eckel, Chaoyin Zhou, John H Martin, Alan J Jacobsen, William B Carter, Tobias A Schaedler

Affiliations

  1. HRL Laboratories, LLC, 3011 Malibu Canyon Road, Malibu, CA 90265, USA.
  2. HRL Laboratories, LLC, 3011 Malibu Canyon Road, Malibu, CA 90265, USA. [email protected].

PMID: 26721993 DOI: 10.1126/science.aad2688

Abstract

The extremely high melting point of many ceramics adds challenges to additive manufacturing as compared with metals and polymers. Because ceramics cannot be cast or machined easily, three-dimensional (3D) printing enables a big leap in geometrical flexibility. We report preceramic monomers that are cured with ultraviolet light in a stereolithography 3D printer or through a patterned mask, forming 3D polymer structures that can have complex shape and cellular architecture. These polymer structures can be pyrolyzed to a ceramic with uniform shrinkage and virtually no porosity. Silicon oxycarbide microlattice and honeycomb cellular materials fabricated with this approach exhibit higher strength than ceramic foams of similar density. Additive manufacturing of such materials is of interest for propulsion components, thermal protection systems, porous burners, microelectromechanical systems, and electronic device packaging.

Copyright © 2016, American Association for the Advancement of Science.

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