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Son C, Inagaki A. Synthesis and photocatalytic activity of a naphthyl-substituted photosensitizing BINAP-palladium complex. Dalton Trans. 2016;45(4):1331-4doi: 10.1039/c5dt04228c.
Son, C., & Inagaki, A. (2016). Synthesis and photocatalytic activity of a naphthyl-substituted photosensitizing BINAP-palladium complex. Dalton transactions (Cambridge, England : 2003), 45(4), 1331-4. https://doi.org/10.1039/c5dt04228c
Son, Changsu, and Inagaki, Akiko. "Synthesis and photocatalytic activity of a naphthyl-substituted photosensitizing BINAP-palladium complex." Dalton transactions (Cambridge, England : 2003) vol. 45,4 (2016): 1331-4. doi: https://doi.org/10.1039/c5dt04228c
Son C, Inagaki A. Synthesis and photocatalytic activity of a naphthyl-substituted photosensitizing BINAP-palladium complex. Dalton Trans. 2016 Jan 28;45(4):1331-4. doi: 10.1039/c5dt04228c. Epub 2016 Jan 04. PMID: 26727516.
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Dalton Trans. 2016 Jan 28;45(4):1331-4. doi: 10.1039/c5dt04228c. Epub 2016 Jan 04.

Synthesis and photocatalytic activity of a naphthyl-substituted photosensitizing BINAP-palladium complex.

Dalton transactions (Cambridge, England : 2003)

Changsu Son, Akiko Inagaki

Affiliations

  1. Graduate School of Science and Engineering, Tokyo Metropolitan University, Minami-Osawa 1-1, Hachioji, Tokyo, 192-0397, Japan. [email protected].

PMID: 26727516 DOI: 10.1039/c5dt04228c

Abstract

A novel light-active Pd complex having a BINAP ligand with 2-naphthyl substituents on the phosphines was synthesized and characterized. The complex showed good polymerization activity toward 4-methoxystyrene during irradiation (λ = 395 nm) and the reaction progress can be controlled by ON-OFF switching of the light source. Mechanistic investigations strongly suggest a coordination-insertion mechanism.

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