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Sensors (Basel). 2015 Nov 30;15(12):29950-7. doi: 10.3390/s151229775.

A Single Eu-Doped In₂O₃ Nanobelt Device for Selective H₂S Detection.

Sensors (Basel, Switzerland)

Weiwu Chen, Yingkai Liu, Zhaojun Qin, Yuemei Wu, Shuanghui Li, Peng Ai

Affiliations

  1. Institute of Physics and Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. [email protected].
  2. Institute of Physics and Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. [email protected].
  3. Institute of Physics and Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. [email protected].
  4. Institute of Physics and Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. [email protected].
  5. Institute of Physics and Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. [email protected].
  6. Institute of Physics and Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. [email protected].

PMID: 26633404 PMCID: PMC4721696 DOI: 10.3390/s151229775

Abstract

Eu-doped In₂O₃ nanobelts (Eu-In₂O₃ NBs) and pure In₂O₃ nanobelts (In₂O₃ NBs) are synthesized by the carbon thermal reduction method. Single nanobelt sensors are fabricated via an ion beam deposition system with a mesh-grid mask. The gas-sensing response properties of the Eu-In₂O₃ NB device and its undoped counterpart are investigated with several kinds of gases (including H₂S, CO, NO₂, HCHO, and C₂H₅OH) at different concentrations and different temperatures. It is found that the response of the Eu-In₂O₃ NB device to 100 ppm of H₂S is the best among these gases and the sensitivity reaches 5.74, which is five times that of pure In₂O₃ NB at 260 °C. We also found that the former has an excellent sensitive response and great selectivity to H₂S compared to the latter. Besides, there is a linear relationship between the response and H₂S concentration when its concentration changes from 5 to 100 ppm and from 100 to 1000 ppm. The response/recovery time is quite short and remains stable with an increase of H₂S concentration. These results mean that the doping of Eu can improve the gas-sensing performance of In₂O₃ NB effectually.

Keywords: Eu-doped In2O3; H2S; gas sensor; single nanobelt

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