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Opt Express. 2015 Nov 30;23(24):A1491-8. doi: 10.1364/OE.23.0A1491.

Ultrathin planar hematite film for solar photoelectrochemical water splitting.

Optics express

Dong Liu, David M Bierman, Andrej Lenert, Hai-Tong Yu, Zhen Yang, Evelyn N Wang, Yuan-Yuan Duan

PMID: 26698797 DOI: 10.1364/OE.23.0A1491

Abstract

Hematite holds promise for photoelectrochemical (PEC) water splitting due to its stability, low-cost, abundance and appropriate bandgap. However, it suffers from a mismatch between the hole diffusion length and light penetration length. We have theoretically designed and characterized an ultrathin planar hematite/silver nanohole array/silver substrate photoanode. Due to the supported destructive interference and surface plasmon resonance, photons are efficiently absorbed in an ultrathin hematite film. Compared with ultrathin hematite photoanodes with nanophotonic structures, this photoanode has comparable photon absorption but with intrinsically lower recombination losses due to its planar structure and promises to exceed the state-of-the-art photocurrent of hematite photoanodes.

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