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Kawahara R, Niinomi K, Kondo JN, et al. A functional mesoporous ionic crystal based on polyoxometalate. Dalton Trans. 2016;45(7):2805-9doi: 10.1039/c5dt04556h.
Kawahara, R., Niinomi, K., Kondo, J. N., Hibino, M., Mizuno, N., & Uchida, S. (2016). A functional mesoporous ionic crystal based on polyoxometalate. Dalton transactions (Cambridge, England : 2003), 45(7), 2805-9. https://doi.org/10.1039/c5dt04556h
Kawahara, Ryosuke, et al. "A functional mesoporous ionic crystal based on polyoxometalate." Dalton transactions (Cambridge, England : 2003) vol. 45,7 (2016): 2805-9. doi: https://doi.org/10.1039/c5dt04556h
Kawahara R, Niinomi K, Kondo JN, Hibino M, Mizuno N, Uchida S. A functional mesoporous ionic crystal based on polyoxometalate. Dalton Trans. 2016 Feb 21;45(7):2805-9. doi: 10.1039/c5dt04556h. Epub 2016 Jan 25. PMID: 26804446.
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Dalton Trans. 2016 Feb 21;45(7):2805-9. doi: 10.1039/c5dt04556h. Epub 2016 Jan 25.

A functional mesoporous ionic crystal based on polyoxometalate.

Dalton transactions (Cambridge, England : 2003)

Ryosuke Kawahara, Kazuma Niinomi, Junko N Kondo, Mitsuhiro Hibino, Noritaka Mizuno, Sayaka Uchida

Affiliations

  1. Department of Basic Science, School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan. [email protected].

PMID: 26804446 DOI: 10.1039/c5dt04556h

Abstract

A mesoporous ionic crystal is synthesized with a polyoxometalate and a macrocation with polar cyano groups. The compound possesses one-dimensional mesopores with an opening of 3.0 × 2.0 nm. The compound shows high proton conductivity and catalytic activity, which are due to the water molecules in the mesopores.

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