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Godemann C, Spannenberg A, Beweries T. Crystal structure of 1-hy-droxy-2,2,6,6-tetra-methyl-piperidin-1-ium tri-fluoro-methane-sulfonate. Acta Crystallogr E Crystallogr Commun. 2015;71:o921doi: 10.1107/S2056989015020897.
Godemann, C., Spannenberg, A., & Beweries, T. (2015). Crystal structure of 1-hy-droxy-2,2,6,6-tetra-methyl-piperidin-1-ium tri-fluoro-methane-sulfonate. Acta crystallographica. Section E, Crystallographic communications, 71o921. https://doi.org/10.1107/S2056989015020897
Godemann, Christian, et al. "Crystal structure of 1-hy-droxy-2,2,6,6-tetra-methyl-piperidin-1-ium tri-fluoro-methane-sulfonate." Acta crystallographica. Section E, Crystallographic communications vol. 71 (2015): o921. doi: https://doi.org/10.1107/S2056989015020897
Godemann C, Spannenberg A, Beweries T. Crystal structure of 1-hy-droxy-2,2,6,6-tetra-methyl-piperidin-1-ium tri-fluoro-methane-sulfonate. Acta Crystallogr E Crystallogr Commun. 2015 Nov 07;71:o921. doi: 10.1107/S2056989015020897. eCollection 2015 Dec 01. PMID: 26870528; PMCID: PMC4719881.
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Acta Crystallogr E Crystallogr Commun. 2015 Nov 07;71:o921. doi: 10.1107/S2056989015020897. eCollection 2015 Dec 01.

Crystal structure of 1-hy-droxy-2,2,6,6-tetra-methyl-piperidin-1-ium tri-fluoro-methane-sulfonate.

Acta crystallographica. Section E, Crystallographic communications

Christian Godemann, Anke Spannenberg, Torsten Beweries

Affiliations

  1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.

PMID: 26870528 PMCID: PMC4719881 DOI: 10.1107/S2056989015020897

Abstract

In the cation of the title salt, C9H20NO(+)·CF3O3S(-), the six-membered heterocyclic ring displays a chair conformation. In the crystal, centrosymmetric pairs of cations and anions are linked by N-H⋯O and O-H⋯O hydrogen bonds to form rings with a R 4 (4)(14) graph-set motif.

Keywords: TEMPO; ammonium salt; crystal structure; hydrogen bonding; triflate

References

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