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Sasaki T, Hashimoto S, Nogami N, et al. Dismantlable Thermosetting Adhesives Composed of a Cross-Linkable Poly(olefin sulfone) with a Photobase Generator. ACS Appl Mater Interfaces. 2016;8(8):5580-5doi: 10.1021/acsami.5b10110.
Sasaki, T., Hashimoto, S., Nogami, N., Sugiyama, Y., Mori, M., Naka, Y., & Le, K. V. (2016). Dismantlable Thermosetting Adhesives Composed of a Cross-Linkable Poly(olefin sulfone) with a Photobase Generator. ACS applied materials & interfaces, 8(8), 5580-5. https://doi.org/10.1021/acsami.5b10110
Sasaki, Takeo, et al. "Dismantlable Thermosetting Adhesives Composed of a Cross-Linkable Poly(olefin sulfone) with a Photobase Generator." ACS applied materials & interfaces vol. 8,8 (2016): 5580-5. doi: https://doi.org/10.1021/acsami.5b10110
Sasaki T, Hashimoto S, Nogami N, Sugiyama Y, Mori M, Naka Y, Le KV. Dismantlable Thermosetting Adhesives Composed of a Cross-Linkable Poly(olefin sulfone) with a Photobase Generator. ACS Appl Mater Interfaces. 2016 Mar 02;8(8):5580-5. doi: 10.1021/acsami.5b10110. Epub 2016 Feb 19. PMID: 26872271.
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ACS Appl Mater Interfaces. 2016 Mar 02;8(8):5580-5. doi: 10.1021/acsami.5b10110. Epub 2016 Feb 19.

Dismantlable Thermosetting Adhesives Composed of a Cross-Linkable Poly(olefin sulfone) with a Photobase Generator.

ACS applied materials & interfaces

Takeo Sasaki, Shouta Hashimoto, Nana Nogami, Yuichi Sugiyama, Madoka Mori, Yumiko Naka, Khoa V Le

Affiliations

  1. Department of Chemistry, Faculty of Science, Tokyo University of Science 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.

PMID: 26872271 DOI: 10.1021/acsami.5b10110

Abstract

A novel photodetachable adhesive was prepared using a photodepolymerizable cross-linked poly(olefin sulfone). A mixture of a cross-linkable poly(olefin sulfone), a cross-linking reagent, and a photobase generator functioned as a thermosetting adhesive and exhibited high adhesive strength on quartz plates comparable to that obtained for commercially available epoxy adhesives. The cured resin was stable in the absence of UV light irradiation but completely lost its adhesive strength upon exposure of glued quartz plates to UV light in conjunction with heating to 100 °C.

Keywords: dismantlable adhesives; photobase generator; photoinduced depolymerization; poly(olefin sulfone)s; thermosetting adhesives

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