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Sci Rep. 2016 Feb 15;6:20781. doi: 10.1038/srep20781.

Magnetoelectric effect in organic molecular solids.

Scientific reports

Makoto Naka, Sumio Ishihara

Affiliations

  1. Department of Physics, Tohoku University, Sendai 980-8578, Japan.

PMID: 26876424 PMCID: PMC4753515 DOI: 10.1038/srep20781

Abstract

The Magnetoelectric (ME) effect in solids is a prominent cross correlation phenomenon, in which the electric field (E) controls the magnetization (M) and the magnetic field (H) controls the electric polarization (P). A rich variety of ME effects and their potential in practical applications have been investigated so far within the transition-metal compounds. Here, we report a possible way to realize the ME effect in organic molecular solids, in which two molecules build a dimer unit aligned on a lattice site. The linear ME effect is predicted in a long-range ordered state of spins and electric dipoles, as well as in a disordered state. One key of the ME effect is a hidden ferroic order of the spin-charge composite object. We provide a new guiding principle of the ME effect in materials without transition-metal elements, which may lead to flexible and lightweight multifunctional materials.

References

  1. Nat Mater. 2012 Sep;11(9):755-8 - PubMed
  2. Nature. 2003 Nov 6;426(6962):55-8 - PubMed
  3. Phys Rev Lett. 2012 Mar 2;108(9):096402 - PubMed
  4. Phys Rev Lett. 2005 Jul 29;95(5):057205 - PubMed
  5. Nat Mater. 2007 Jan;6(1):13-20 - PubMed
  6. Phys Rev Lett. 2006 Feb 17;96(6):067601 - PubMed
  7. Nat Commun. 2012;3:904 - PubMed
  8. Science. 2004 Jan 30;303(5658):661-3 - PubMed
  9. Phys Rev Lett. 2000 Aug 21;85(8):1698-701 - PubMed
  10. Phys Rev Lett. 2009 Dec 31;103(26):266401 - PubMed
  11. Chem Rev. 2004 Nov;104(11):5005-36 - PubMed
  12. Phys Rev Lett. 2001 Apr 30;86(18):4080-3 - PubMed
  13. Phys Rev Lett. 2009 Apr 10;102(14):146805 - PubMed
  14. Science. 1991 Jun 14;252(5012):1509-14 - PubMed

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