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Bittner DM, Zaleski DP, Tew DP, et al. Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase. Angew Chem Int Ed Engl. 2016;55(11):3768-71doi: 10.1002/anie.201511646.
Bittner, D. M., Zaleski, D. P., Tew, D. P., Walker, N. R., & Legon, A. C. (2016). Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase. Angewandte Chemie (International ed. in English), 55(11), 3768-71. https://doi.org/10.1002/anie.201511646
Bittner, Dror M, et al. "Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase." Angewandte Chemie (International ed. in English) vol. 55,11 (2016): 3768-71. doi: https://doi.org/10.1002/anie.201511646
Bittner DM, Zaleski DP, Tew DP, Walker NR, Legon AC. Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase. Angew Chem Int Ed Engl. 2016 Mar 07;55(11):3768-71. doi: 10.1002/anie.201511646. Epub 2016 Feb 16. PMID: 26879473; PMCID: PMC4797365.
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Angew Chem Int Ed Engl. 2016 Mar 07;55(11):3768-71. doi: 10.1002/anie.201511646. Epub 2016 Feb 16.

Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase.

Angewandte Chemie (International ed. in English)

Dror M Bittner, Daniel P Zaleski, David P Tew, Nicholas R Walker, Anthony C Legon

Affiliations

  1. School of Chemistry, Bedson Building, Newcastle University, Newcastle upon Tyne, Tyne and Wear, NE1 7RU, UK.
  2. Argonne National Laboratory, Chemical Sciences and Engineering, 9700 S. Cass Ave., Bldg. 200, Lemont, IL, 60439, USA.
  3. School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK.
  4. School of Chemistry, Bedson Building, Newcastle University, Newcastle upon Tyne, Tyne and Wear, NE1 7RU, UK. [email protected].
  5. School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK. [email protected].

PMID: 26879473 PMCID: PMC4797365 DOI: 10.1002/anie.201511646

Abstract

Carbenes of platinum and palladium, PtC3 and PdC3 , were generated in the gas phase through laser vaporization of a metal target in the presence of a low concentration of a hydrocarbon precursor undergoing supersonic expansion. Rotational spectroscopy and ab initio calculations confirm that both molecules are linear. The geometry of PtC3 was accurately determined by fitting to the experimental moments of inertia of twenty-six isotopologues. The results are consistent with the proposal of an autogenic isolobal relationship between O, Au(+) , and Pt atoms.

© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: ab initio calculations; carbenes; palladium; platinum; rotational spectroscopy

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